SYNTHESIS AND CHARACTERIZATION OF Fe（II）-COORDINATED PS-b-P[NIPAM-co-（VBC-Fe-DMAP）] BLOCK COPOLYMERS

SYNTHESIS AND CHARACTERIZATION OF Fe（II）-COORDINATED PS-b-P[NIPAM-co-（VBC-Fe-DMAP）] BLOCK COPOLYMERS

In this work, a new type of block polymers, polystyrene-b-poly[（N-isopropyl acrylamide）-co-（vinyl benzyl chloride）] （PS-b-P（NIPAM-co-VBC））, was prepared via reversible addition fragmentation transfer polymerization, then pentacyano（4-（dimethylamino pyridine））ferrate （Fe-DMAP） was attached to VBC uni...

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Veröffentlicht in:高分子科学：英文版 2012, Vol.30 (5), p.674-681
1. Verfasser: Kai Cao Jun-ting Xu Xiao-song Wang
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Sprache:eng
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DMAP
N-异丙基丙烯酰胺
合成
嵌段共聚物
嵌段聚合物
表征
高铁酸盐
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description In this work, a new type of block polymers, polystyrene-b-poly[（N-isopropyl acrylamide）-co-（vinyl benzyl chloride）] （PS-b-P（NIPAM-co-VBC））, was prepared via reversible addition fragmentation transfer polymerization, then pentacyano（4-（dimethylamino pyridine））ferrate （Fe-DMAP） was attached to VBC units through a quatemization process. The Fe（II）-coordinated PS-b-P[NIPAM-co-（VBC-Fe-DMAP）] block copolymers were characterized by 1H-NMR, FT-IR and TGA. The self-assembly behavior of the block copolymers was also investigated and the micelle morphology was characterized by TEM. It was found that the PS-b-P（NIPAM-co-VBC） block polymer and Fe-coordinated block copolymer could both form spherical micelles in DMF/MeOH mixed solvent.
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subjects DMAP
N-异丙基丙烯酰胺
合成
嵌段共聚物
嵌段聚合物
表征
高铁酸盐
title SYNTHESIS AND CHARACTERIZATION OF Fe（II）-COORDINATED PS-b-P[NIPAM-co-（VBC-Fe-DMAP）] BLOCK COPOLYMERS
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