A hybrid carboxylate-water decamer with a discrete octameric water moiety self-assembled in a 2D copper（II） coordination polymer
An octameric water moiety which consists of a chairlike water hexamer and two pendent water molecules in the 1,4-diaxial positions and shows a similar structure to the hydrocarbon （lr,4r）-1,4-dimethylcyclohexane, is unambiguously trapped in a 2D Cu（II） mixed-ligand coordination polymer, {[Cu2（bpp）2（...
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| Veröffentlicht in: | 中国科学：化学英文版 2012, Vol.55 (7), p.1213-1219 |
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| container_title | 中国科学：化学英文版 |
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| creator | LUO GengGeng WU DongLiang LIU Li LI DongXu ZHAO QingHua XIAO ZiJing DAI JingCao |
| description | An octameric water moiety which consists of a chairlike water hexamer and two pendent water molecules in the 1,4-diaxial positions and shows a similar structure to the hydrocarbon （lr,4r）-1,4-dimethylcyclohexane, is unambiguously trapped in a 2D Cu（II） mixed-ligand coordination polymer, {[Cu2（bpp）2（HzO）2（bpda）2]＇6H2O}n （1） （bpp = 1,3-bis（4-pyridyl）propane and H2bpda = 2,2＇-biphenyldicarboxylic acid）. The water octamer can be extended into a hybrid carboxylate-water decamer when carboxylic oxygen atoms from bpda2- are involved. Interestingly, the present hybrid decamer bears a similar structural topology to a butterfly （H2O）10 cluster. The reversible dehydration/hydration of 1 is determined by X-ray powder diffraction studies. |
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The water octamer can be extended into a hybrid carboxylate-water decamer when carboxylic oxygen atoms from bpda2- are involved. Interestingly, the present hybrid decamer bears a similar structural topology to a butterfly （H2O）10 cluster. The reversible dehydration/hydration of 1 is determined by X-ray powder diffraction studies.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><language>eng</language><subject>二维离散 ; 水基 ; 混合配体 ; 碱基 ; 自组装 ; 配位聚合物 ; 酸水 ; 铜</subject><ispartof>中国科学：化学英文版, 2012, Vol.55 (7), p.1213-1219</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/60113X/60113X.jpg</thumbnail><link.rule.ids>314,780,784,4021</link.rule.ids></links><search><creatorcontrib>LUO GengGeng WU DongLiang LIU Li LI DongXu ZHAO QingHua XIAO ZiJing DAI JingCao</creatorcontrib><title>A hybrid carboxylate-water decamer with a discrete octameric water moiety self-assembled in a 2D copper（II） coordination polymer</title><title>中国科学：化学英文版</title><addtitle>SCIENCE CHINA Chemistry</addtitle><description>An octameric water moiety which consists of a chairlike water hexamer and two pendent water molecules in the 1,4-diaxial positions and shows a similar structure to the hydrocarbon （lr,4r）-1,4-dimethylcyclohexane, is unambiguously trapped in a 2D Cu（II） mixed-ligand coordination polymer, {[Cu2（bpp）2（HzO）2（bpda）2]＇6H2O}n （1） （bpp = 1,3-bis（4-pyridyl）propane and H2bpda = 2,2＇-biphenyldicarboxylic acid）. The water octamer can be extended into a hybrid carboxylate-water decamer when carboxylic oxygen atoms from bpda2- are involved. Interestingly, the present hybrid decamer bears a similar structural topology to a butterfly （H2O）10 cluster. The reversible dehydration/hydration of 1 is determined by X-ray powder diffraction studies.</description><subject>二维离散</subject><subject>水基</subject><subject>混合配体</subject><subject>碱基</subject><subject>自组装</subject><subject>配位聚合物</subject><subject>酸水</subject><subject>铜</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNqNjE1uwjAQhS3USqCWO0wPYClxAiHLqj8q--6RYw9kkGMH2xL1vov2TtyJK9QVHIBZzHvz9L2ZsFm5Wra8XDXFXfbLpuaNaMspm4ewL_JUVSGaxYx9P0OfOk8alPSd-0pGRuTHvDxoVHLIeqTYgwRNQXmMCE7F_5wUXLjBEcYEAc2WyxBw6AxqIJs74hWUG0f059PPen0-_ebTeU1WRnIWRmdS_vTI7rfSBJxf9YE9vb99vnxw1Tu7O5DdbUZPg_RpU4u6rRatqG5h_gAhYVVC</recordid><startdate>2012</startdate><enddate>2012</enddate><creator>LUO GengGeng WU DongLiang LIU Li LI DongXu ZHAO QingHua XIAO ZiJing DAI JingCao</creator><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope></search><sort><creationdate>2012</creationdate><title>A hybrid carboxylate-water decamer with a discrete octameric water moiety self-assembled in a 2D copper（II） coordination polymer</title><author>LUO GengGeng WU DongLiang LIU Li LI DongXu ZHAO QingHua XIAO ZiJing DAI JingCao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-chongqing_primary_424935923</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>二维离散</topic><topic>水基</topic><topic>混合配体</topic><topic>碱基</topic><topic>自组装</topic><topic>配位聚合物</topic><topic>酸水</topic><topic>铜</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>LUO GengGeng WU DongLiang LIU Li LI DongXu ZHAO QingHua XIAO ZiJing DAI JingCao</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><jtitle>中国科学：化学英文版</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>LUO GengGeng WU DongLiang LIU Li LI DongXu ZHAO QingHua XIAO ZiJing DAI JingCao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A hybrid carboxylate-water decamer with a discrete octameric water moiety self-assembled in a 2D copper（II） coordination polymer</atitle><jtitle>中国科学：化学英文版</jtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><date>2012</date><risdate>2012</risdate><volume>55</volume><issue>7</issue><spage>1213</spage><epage>1219</epage><pages>1213-1219</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>An octameric water moiety which consists of a chairlike water hexamer and two pendent water molecules in the 1,4-diaxial positions and shows a similar structure to the hydrocarbon （lr,4r）-1,4-dimethylcyclohexane, is unambiguously trapped in a 2D Cu（II） mixed-ligand coordination polymer, {[Cu2（bpp）2（HzO）2（bpda）2]＇6H2O}n （1） （bpp = 1,3-bis（4-pyridyl）propane and H2bpda = 2,2＇-biphenyldicarboxylic acid）. The water octamer can be extended into a hybrid carboxylate-water decamer when carboxylic oxygen atoms from bpda2- are involved. Interestingly, the present hybrid decamer bears a similar structural topology to a butterfly （H2O）10 cluster. The reversible dehydration/hydration of 1 is determined by X-ray powder diffraction studies.</abstract></addata></record> |
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| ispartof | 中国科学：化学英文版, 2012, Vol.55 (7), p.1213-1219 |
| issn | 1674-7291 1869-1870 |
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| source | ProQuest Central Essentials; ProQuest Central (Alumni Edition); ProQuest Central Student; ProQuest Central Korea; ProQuest Central UK/Ireland; Alma/SFX Local Collection; SpringerLink Journals - AutoHoldings; ProQuest Central |
| subjects | 二维离散 水基 混合配体 碱基 自组装 配位聚合物 酸水 铜 |
| title | A hybrid carboxylate-water decamer with a discrete octameric water moiety self-assembled in a 2D copper（II） coordination polymer |
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