Hollow calcium carbonate microspheres prepared in the presence of polyoxyethylene (20) sorbitan monolaurate and sodium dodecyl sulfate

Hollow calcium carbonate ( CaCO3 ) microspheres were prepared in aqueous solution with the presence of polyoxyethylene (20) sorbitan monolaurate ( Tween20 ) and sodium dodecyl sulfate (SDS). The microspheres were characterized with X-ray diffraction (XRD) , scanning electron microscopy (SEM) and tra...

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Veröffentlicht in:北京理工大学学报:英文版 2012, Vol.21 (1), p.112-117
1. Verfasser: 游超 张强 赵芸 矫庆泽
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description Hollow calcium carbonate ( CaCO3 ) microspheres were prepared in aqueous solution with the presence of polyoxyethylene (20) sorbitan monolaurate ( Tween20 ) and sodium dodecyl sulfate (SDS). The microspheres were characterized with X-ray diffraction (XRD) , scanning electron microscopy (SEM) and transmission electron microscope (TEM). The X-ray diffraction data showed that the hollow CaCO3 microsphere consisted of calcite crystals. The influence of Tween20 and SDS concentrations on the morphology of CaCO3 crystals was investigated. The results suggested that the "core-shell model" of Tween20/SDS micelle aggregated as templates, which could control the growth of hollow CaCO3 microspheres. The interaction between mixed surfactants and calcium ions played a critical role in organizing calcium carbonate in microscopic level.
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title Hollow calcium carbonate microspheres prepared in the presence of polyoxyethylene (20) sorbitan monolaurate and sodium dodecyl sulfate
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