An Efficient and Green One-pot Synthesis of 12-Aryl-8,9,10,12-tetra hyd robenzo[a]xanthen-11 -one Deriva- tives Promoted by Sulfamic Acid in [BMIM]BF4 Ionic Liquid
An efficient and green procedure for the synthesis of novel 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen- 11- one derivatives has been described through one-pot condensation of 2-naphthol, arylaldehyde and 5,5-dimethyl- cyclohexane-l,3-dione in the presence of sulfamic acid (NH2SO3H) in ionic liquid...
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Veröffentlicht in: | 中国化学:英文版 2012, Vol.30 (2), p.362-366 |
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description | An efficient and green procedure for the synthesis of novel 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen- 11- one derivatives has been described through one-pot condensation of 2-naphthol, arylaldehyde and 5,5-dimethyl- cyclohexane-l,3-dione in the presence of sulfamic acid (NH2SO3H) in ionic liquid 1-n-butyl-3-methylimidazolium tetrafluoroborate ([BMIM]BF4). These reactions proceed with good yields under short reaction time. Furthermore, the green catalytic system can be recycled specific times with no decreases in yields and reaction rates. |
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subjects | BF4 一锅法合成 反应时间 氨基磺酸 离子液体 芳基 路政 酮衍生物 |
title | An Efficient and Green One-pot Synthesis of 12-Aryl-8,9,10,12-tetra hyd robenzo[a]xanthen-11 -one Deriva- tives Promoted by Sulfamic Acid in [BMIM]BF4 Ionic Liquid |
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