Structural Regularities of the Transition Metal Complexes Containing o-Benzenedithiol （H2bdt）——Synthesis and Structure of Fe3（bdt）3（PBu3n）3
Complex Fe3（bdt）3（PBu3n）3 was synthesized in the presence of PBu3n and the structural regularities in a series of transition metal complexes containing bdtH2 ligand were summarized. The title complex crystallizes in the triclinic space group P-, Mr=1195.19, cell parameters: a=13.283（3）, b=20.115（5）,...
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| Veröffentlicht in: | 中国科学：化学英文版 1993 (8), p.912-919 |
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| container_title | 中国科学：化学英文版 |
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| creator | 康北笙 徐勇进 吴达旭 彭金海 洪茂椿 翁林红 陈学太 刘汉钦 |
| description | Complex Fe3（bdt）3（PBu3n）3 was synthesized in the presence of PBu3n and the structural regularities in a series of transition metal complexes containing bdtH2 ligand were summarized. The title complex crystallizes in the triclinic space group P-, Mr=1195.19, cell parameters: a=13.283（3）, b=20.115（5）, c=13.156（3）, （?）=90.33（2）, β= 116.47 （1）, γ=92.19（2）°, V=3143.5（2.7）3, Z=2, dc=1.26g/cm3. The structure was solved by direct methods from 4122 unique reflections with I>4σ（I） and reached the final convergence factor of R（Rw） = 0.053 （0.060）. The complex exhibits strong paramagnetism. |
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The title complex crystallizes in the triclinic space group P-, Mr=1195.19, cell parameters: a=13.283（3）, b=20.115（5）, c=13.156（3）, （?）=90.33（2）, β= 116.47 （1）, γ=92.19（2）°, V=3143.5（2.7）3, Z=2, dc=1.26g/cm3. The structure was solved by direct methods from 4122 unique reflections with I&gt;4σ（I） and reached the final convergence factor of R（Rw） = 0.053 （0.060）. The complex exhibits strong paramagnetism.</description><identifier>ISSN: 1674-7291</identifier><identifier>EISSN: 1869-1870</identifier><language>eng</language><subject>and ; cluster ; complex ; compound ; coordinated ; iron ; ligand ; o-benzenedithiol ; phosphine-mixed ; regularity ; structural ; thiolate ; trinuclear</subject><ispartof>中国科学：化学英文版, 1993 (8), p.912-919</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/60113X/60113X.jpg</thumbnail><link.rule.ids>315,782,786,4026</link.rule.ids></links><search><creatorcontrib>康北笙 徐勇进 吴达旭 彭金海 洪茂椿 翁林红 陈学太 刘汉钦</creatorcontrib><title>Structural Regularities of the Transition Metal Complexes Containing o-Benzenedithiol （H2bdt）——Synthesis and Structure of Fe3（bdt）3（PBu3n）3</title><title>中国科学：化学英文版</title><addtitle>SCIENCE CHINA Chemistry</addtitle><description>Complex Fe3（bdt）3（PBu3n）3 was synthesized in the presence of PBu3n and the structural regularities in a series of transition metal complexes containing bdtH2 ligand were summarized. The title complex crystallizes in the triclinic space group P-, Mr=1195.19, cell parameters: a=13.283（3）, b=20.115（5）, c=13.156（3）, （?）=90.33（2）, β= 116.47 （1）, γ=92.19（2）°, V=3143.5（2.7）3, Z=2, dc=1.26g/cm3. The structure was solved by direct methods from 4122 unique reflections with I&gt;4σ（I） and reached the final convergence factor of R（Rw） = 0.053 （0.060）. The complex exhibits strong paramagnetism.</description><subject>and</subject><subject>cluster</subject><subject>complex</subject><subject>compound</subject><subject>coordinated</subject><subject>iron</subject><subject>ligand</subject><subject>o-benzenedithiol</subject><subject>phosphine-mixed</subject><subject>regularity</subject><subject>structural</subject><subject>thiolate</subject><subject>trinuclear</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqNjcFKAzEQhoMoWGzfIeB5IdnsdrfXLpZeBLG9l7Q73Y2kk5pkwXryqHdvvkqfxhfoK3QW9e4wMB8_H_NfsIEsx5NEloW4JB4XWVKkE3nNRiE8CRqlRFrkA_a1iL7bxM5ryx-h6az2JhoI3G15bIEvvcZAiUN-D5Gkyu32Fl7IqBxGbdBgw10yBXwFhNrE1jjLT8f3ebqu4-n48f32Sbs4IL0LJnCNNf8rhb5mBor0H7mnh2mnsOchu9pqG2D0e2_Y7exuWc2TTeuweabi1d6bnfaHVSaEzMo8l7n6n3UGcANkjQ</recordid><startdate>1993</startdate><enddate>1993</enddate><creator>康北笙 徐勇进 吴达旭 彭金海 洪茂椿 翁林红 陈学太 刘汉钦</creator><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W94</scope><scope>~WA</scope></search><sort><creationdate>1993</creationdate><title>Structural Regularities of the Transition Metal Complexes Containing o-Benzenedithiol （H2bdt）——Synthesis and Structure of Fe3（bdt）3（PBu3n）3</title><author>康北笙 徐勇进 吴达旭 彭金海 洪茂椿 翁林红 陈学太 刘汉钦</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-chongqing_primary_40014855153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>and</topic><topic>cluster</topic><topic>complex</topic><topic>compound</topic><topic>coordinated</topic><topic>iron</topic><topic>ligand</topic><topic>o-benzenedithiol</topic><topic>phosphine-mixed</topic><topic>regularity</topic><topic>structural</topic><topic>thiolate</topic><topic>trinuclear</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>康北笙 徐勇进 吴达旭 彭金海 洪茂椿 翁林红 陈学太 刘汉钦</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-自然科学</collection><collection>中文科技期刊数据库- 镜像站点</collection><jtitle>中国科学：化学英文版</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>康北笙 徐勇进 吴达旭 彭金海 洪茂椿 翁林红 陈学太 刘汉钦</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural Regularities of the Transition Metal Complexes Containing o-Benzenedithiol （H2bdt）——Synthesis and Structure of Fe3（bdt）3（PBu3n）3</atitle><jtitle>中国科学：化学英文版</jtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><date>1993</date><risdate>1993</risdate><issue>8</issue><spage>912</spage><epage>919</epage><pages>912-919</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>Complex Fe3（bdt）3（PBu3n）3 was synthesized in the presence of PBu3n and the structural regularities in a series of transition metal complexes containing bdtH2 ligand were summarized. The title complex crystallizes in the triclinic space group P-, Mr=1195.19, cell parameters: a=13.283（3）, b=20.115（5）, c=13.156（3）, （?）=90.33（2）, β= 116.47 （1）, γ=92.19（2）°, V=3143.5（2.7）3, Z=2, dc=1.26g/cm3. The structure was solved by direct methods from 4122 unique reflections with I&gt;4σ（I） and reached the final convergence factor of R（Rw） = 0.053 （0.060）. The complex exhibits strong paramagnetism.</abstract></addata></record> |
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| ispartof | 中国科学：化学英文版, 1993 (8), p.912-919 |
| issn | 1674-7291 1869-1870 |
| language | eng |
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| source | Alma/SFX Local Collection |
| subjects | and cluster complex compound coordinated iron ligand o-benzenedithiol phosphine-mixed regularity structural thiolate trinuclear |
| title | Structural Regularities of the Transition Metal Complexes Containing o-Benzenedithiol （H2bdt）——Synthesis and Structure of Fe3（bdt）3（PBu3n）3 |
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