The Regulation Effect of Phosphoryl Group on Amino Acid Side Chain

The amino acids’ side chains act as the relay device to modulate the chemical reactivity of the N-phosphoryl amino acids. The N-dialkyl phosphoryl cysteine is stable, but the N-dialkyl phosphoryl serine or threoine was converted into many kinds of products at 40℃. The N-dialkyl phosphoryl gltamic ac...

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Veröffentlicht in:	中国科学：化学英文版 1993 (12), p.1451-1458
1. Verfasser:	赵玉芬李艳梅尹应武李援朝
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Sprache:	eng
Schlagworte:	acid aide amino chain’s effect group hexaeoordinate N-phosphoryl partieipation phosphorus phosphoryl regulation
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creator	赵玉芬李艳梅尹应武李援朝
description	The amino acids’ side chains act as the relay device to modulate the chemical reactivity of the N-phosphoryl amino acids. The N-dialkyl phosphoryl cysteine is stable, but the N-dialkyl phosphoryl serine or threoine was converted into many kinds of products at 40℃. The N-dialkyl phosphoryl gltamic acid is a stable compound, while the N-dislkyl phosphoryl aspartic acid was transferred into the peptides, esters and the phosphoryl ester-exchanged products under mild conditions. The N-dialkyl phosphoryl histidine has the similar reactivity through the co-participation of the side chain, carboxyl and phosphoryl groups. A hexacoordinate phosphorus was proposed to account for this differentiation and promotion effect.
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The N-dialkyl phosphoryl cysteine is stable, but the N-dialkyl phosphoryl serine or threoine was converted into many kinds of products at 40℃. The N-dialkyl phosphoryl gltamic acid is a stable compound, while the N-dislkyl phosphoryl aspartic acid was transferred into the peptides, esters and the phosphoryl ester-exchanged products under mild conditions. The N-dialkyl phosphoryl histidine has the similar reactivity through the co-participation of the side chain, carboxyl and phosphoryl groups. 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The N-dialkyl phosphoryl cysteine is stable, but the N-dialkyl phosphoryl serine or threoine was converted into many kinds of products at 40℃. The N-dialkyl phosphoryl gltamic acid is a stable compound, while the N-dislkyl phosphoryl aspartic acid was transferred into the peptides, esters and the phosphoryl ester-exchanged products under mild conditions. The N-dialkyl phosphoryl histidine has the similar reactivity through the co-participation of the side chain, carboxyl and phosphoryl groups. A hexacoordinate phosphorus was proposed to account for this differentiation and promotion effect.</description><subject>acid</subject><subject>aide</subject><subject>amino</subject><subject>chain’s</subject><subject>effect</subject><subject>group</subject><subject>hexaeoordinate</subject><subject>N-phosphoryl</subject><subject>partieipation</subject><subject>phosphorus</subject><subject>phosphoryl</subject><subject>regulation</subject><issn>1674-7291</issn><issn>1869-1870</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqNirEOgjAURRujiUT5h5c4kxQKFEYkqKNRdtJAS2ugxRYH_l4GP8C7nJOcu0FemKV5EGYUb1dPaRzQKA_3yHfuhdcRgiOaeOhcSw4P3n8GNiujoRKCtzMYAXdp3CSNXQa4WvOZYK3FqLSBolUdPFXHoZRM6SPaCTY47v94QKdLVZe3oJVG92-l-2ayamR2aWKMw5jmmCTkv9cXkz06Gw</recordid><startdate>1993</startdate><enddate>1993</enddate><creator>赵玉芬李艳梅尹应武李援朝</creator><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W94</scope><scope>~WA</scope></search><sort><creationdate>1993</creationdate><title>The Regulation Effect of Phosphoryl Group on Amino Acid Side Chain</title><author>赵玉芬李艳梅尹应武李援朝</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-chongqing_primary_40014790353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>acid</topic><topic>aide</topic><topic>amino</topic><topic>chain’s</topic><topic>effect</topic><topic>group</topic><topic>hexaeoordinate</topic><topic>N-phosphoryl</topic><topic>partieipation</topic><topic>phosphorus</topic><topic>phosphoryl</topic><topic>regulation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>赵玉芬李艳梅尹应武李援朝</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-自然科学</collection><collection>中文科技期刊数据库- 镜像站点</collection><jtitle>中国科学：化学英文版</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>赵玉芬李艳梅尹应武李援朝</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Regulation Effect of Phosphoryl Group on Amino Acid Side Chain</atitle><jtitle>中国科学：化学英文版</jtitle><addtitle>SCIENCE CHINA Chemistry</addtitle><date>1993</date><risdate>1993</risdate><issue>12</issue><spage>1451</spage><epage>1458</epage><pages>1451-1458</pages><issn>1674-7291</issn><eissn>1869-1870</eissn><abstract>The amino acids’ side chains act as the relay device to modulate the chemical reactivity of the N-phosphoryl amino acids. The N-dialkyl phosphoryl cysteine is stable, but the N-dialkyl phosphoryl serine or threoine was converted into many kinds of products at 40℃. The N-dialkyl phosphoryl gltamic acid is a stable compound, while the N-dislkyl phosphoryl aspartic acid was transferred into the peptides, esters and the phosphoryl ester-exchanged products under mild conditions. The N-dialkyl phosphoryl histidine has the similar reactivity through the co-participation of the side chain, carboxyl and phosphoryl groups. A hexacoordinate phosphorus was proposed to account for this differentiation and promotion effect.</abstract></addata></record>
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subjects	acid aide amino chain’s effect group hexaeoordinate N-phosphoryl partieipation phosphorus phosphoryl regulation
title	The Regulation Effect of Phosphoryl Group on Amino Acid Side Chain
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