LIGHT SCATTERING OF POLYSACCHARIDE FROM LACQUER IN AQUEOUS SOLUTION
The polysaccharide having weight-average molecular weight Mw=1. 09×105, isolated from the sap of lac trees (Vietnam), was separated into 12 fractions by aqueous-phase preparative gel permeation chromatography. The molecular weights and molecular weight distributions of the fractions were measured in...
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Veröffentlicht in: | 高分子科学:英文版 1989 (3), p.252-257 |
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creator | 张俐娜 杜予民 KUMANOTANI JU |
description | The polysaccharide having weight-average molecular weight Mw=1. 09×105, isolated from the sap of lac trees (Vietnam), was separated into 12 fractions by aqueous-phase preparative gel permeation chromatography. The molecular weights and molecular weight distributions of the fractions were measured in aqueous 0.08M KCl/0.01 M NaAc and 0.4M KCl/0.05M NaAc at pH =7. 6 by light scattering, viscometry and gel permeation chromatography. The Mark-Houwink equation in aqueous 0.08M KCl/0.01M NaAc at 30℃was found to be [η]= 2.28×10-2 Mw0.52 (cm3/g), which indicated the polysaccharide chain in the aqueous solution to be a spherical random coil. |
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The molecular weights and molecular weight distributions of the fractions were measured in aqueous 0.08M KCl/0.01 M NaAc and 0.4M KCl/0.05M NaAc at pH =7. 6 by light scattering, viscometry and gel permeation chromatography. The Mark-Houwink equation in aqueous 0.08M KCl/0.01M NaAc at 30℃was found to be [η]= 2.28×10-2 Mw0.52 (cm3/g), which indicated the polysaccharide chain in the aqueous solution to be a spherical random coil.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><language>eng</language><subject>Chromatography ; Gel ; Lacquer ; Light ; Molecular ; Permeation ; Polysaceharide ; scattering ; Viscosity ; weight</subject><ispartof>高分子科学:英文版, 1989 (3), p.252-257</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/86788X/86788X.jpg</thumbnail><link.rule.ids>314,780,784,4024</link.rule.ids></links><search><creatorcontrib>张俐娜 杜予民 KUMANOTANI JU</creatorcontrib><title>LIGHT SCATTERING OF POLYSACCHARIDE FROM LACQUER IN AQUEOUS SOLUTION</title><title>高分子科学:英文版</title><addtitle>Chinese Journal of Polymer Science</addtitle><description>The polysaccharide having weight-average molecular weight Mw=1. 09×105, isolated from the sap of lac trees (Vietnam), was separated into 12 fractions by aqueous-phase preparative gel permeation chromatography. The molecular weights and molecular weight distributions of the fractions were measured in aqueous 0.08M KCl/0.01 M NaAc and 0.4M KCl/0.05M NaAc at pH =7. 6 by light scattering, viscometry and gel permeation chromatography. The Mark-Houwink equation in aqueous 0.08M KCl/0.01M NaAc at 30℃was found to be [η]= 2.28×10-2 Mw0.52 (cm3/g), which indicated the polysaccharide chain in the aqueous solution to be a spherical random coil.</description><subject>Chromatography</subject><subject>Gel</subject><subject>Lacquer</subject><subject>Light</subject><subject>Molecular</subject><subject>Permeation</subject><subject>Polysaceharide</subject><subject>scattering</subject><subject>Viscosity</subject><subject>weight</subject><issn>0256-7679</issn><issn>1439-6203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNotj09PwyAcholxiXXzO5B4bvIDVhhHgv1DgkVbevC0MFrmjE5dvfjtndHDm-c5Pcl7gTKyZjLnFNglyoAWPBdcyCt0Pc8vAHwtCpEhbU3deNxr5X3ZmbbGrsIPzj71SutGdeauxFXn7rFV-nEoO2xarM7ihh73zg7euHaFFim8ztPNP5fIV6XXTW5dbbSyeZT8K09kBCqKONGCTpGcB4mEwHaRSAhpjFCMgiTJ6SSpBAIboDSGyOQOxCZNbIlu_7Lx-f24_zwc99uP0-EtnL63DOD3rGCC_QA-RkCV</recordid><startdate>1989</startdate><enddate>1989</enddate><creator>张俐娜 杜予民 KUMANOTANI JU</creator><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W94</scope><scope>~WA</scope></search><sort><creationdate>1989</creationdate><title>LIGHT SCATTERING OF POLYSACCHARIDE FROM LACQUER IN AQUEOUS SOLUTION</title><author>张俐娜 杜予民 KUMANOTANI JU</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c96t-f1d0275ce252ec12ec0f1aa3bc190afdc05d71f962e9290108022cac39b078fe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>Chromatography</topic><topic>Gel</topic><topic>Lacquer</topic><topic>Light</topic><topic>Molecular</topic><topic>Permeation</topic><topic>Polysaceharide</topic><topic>scattering</topic><topic>Viscosity</topic><topic>weight</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>张俐娜 杜予民 KUMANOTANI JU</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-自然科学</collection><collection>中文科技期刊数据库- 镜像站点</collection><jtitle>高分子科学:英文版</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>张俐娜 杜予民 KUMANOTANI JU</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>LIGHT SCATTERING OF POLYSACCHARIDE FROM LACQUER IN AQUEOUS SOLUTION</atitle><jtitle>高分子科学:英文版</jtitle><addtitle>Chinese Journal of Polymer Science</addtitle><date>1989</date><risdate>1989</risdate><issue>3</issue><spage>252</spage><epage>257</epage><pages>252-257</pages><issn>0256-7679</issn><eissn>1439-6203</eissn><abstract>The polysaccharide having weight-average molecular weight Mw=1. 09×105, isolated from the sap of lac trees (Vietnam), was separated into 12 fractions by aqueous-phase preparative gel permeation chromatography. The molecular weights and molecular weight distributions of the fractions were measured in aqueous 0.08M KCl/0.01 M NaAc and 0.4M KCl/0.05M NaAc at pH =7. 6 by light scattering, viscometry and gel permeation chromatography. The Mark-Houwink equation in aqueous 0.08M KCl/0.01M NaAc at 30℃was found to be [η]= 2.28×10-2 Mw0.52 (cm3/g), which indicated the polysaccharide chain in the aqueous solution to be a spherical random coil.</abstract><tpages>6</tpages></addata></record> |
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source | Alma/SFX Local Collection |
subjects | Chromatography Gel Lacquer Light Molecular Permeation Polysaceharide scattering Viscosity weight |
title | LIGHT SCATTERING OF POLYSACCHARIDE FROM LACQUER IN AQUEOUS SOLUTION |
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