VISCOSITY BEHAVIOR OF LACQUER POLYSACCHARIDE IN AQUEOUS SOLUTION
The dependence of measured viscosity on NaCl concentration (0.1 to 3.0M), pH (range of 2—13) and cadoxen composition wcad (from 2% to 100%) for the lacquer polysaccharide in NaCl/cadoxen/H2O mixture containing HCl or without were obtained. All the viscosity exponents γin the Mark-Houwink equations u...
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Veröffentlicht in: | 高分子科学:英文版 1991 (1), p.94-100 |
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creator | 邱星屏 张俐娜 杜予民 钱保功 |
description | The dependence of measured viscosity on NaCl concentration (0.1 to 3.0M), pH (range of 2—13) and cadoxen composition wcad (from 2% to 100%) for the lacquer polysaccharide in NaCl/cadoxen/H2O mixture containing HCl or without were obtained. All the viscosity exponents γin the Mark-Houwink equations under three different solvent condition arc close to 0.5. The wcad dependence of reduced viscosity ηsp/c confirms the single strand chain of the polysaccharide. As the γvalues close to 0.5 and values of unperturbed dimension <S2>θ/M and [η] much smaller than those for usual linear polymers, these facts suggest that the polysaccharide chains in the aqueous solutions should be dense random coil owing to the highly branched structure. |
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All the viscosity exponents γin the Mark-Houwink equations under three different solvent condition arc close to 0.5. The wcad dependence of reduced viscosity ηsp/c confirms the single strand chain of the polysaccharide. As the γvalues close to 0.5 and values of unperturbed dimension &lt;S2&gt;θ/M and [η] much smaller than those for usual linear polymers, these facts suggest that the polysaccharide chains in the aqueous solutions should be dense random coil owing to the highly branched structure.</description><identifier>ISSN: 0256-7679</identifier><identifier>EISSN: 1439-6203</identifier><language>eng</language><subject>Aqueous ; cadoxen ; Intrinsic ; Lacquer ; Polysaccharidc ; solution ; viscosity</subject><ispartof>高分子科学:英文版, 1991 (1), p.94-100</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/86788X/86788X.jpg</thumbnail><link.rule.ids>314,780,784,4023</link.rule.ids></links><search><creatorcontrib>邱星屏 张俐娜 杜予民 钱保功</creatorcontrib><title>VISCOSITY BEHAVIOR OF LACQUER POLYSACCHARIDE IN AQUEOUS SOLUTION</title><title>高分子科学:英文版</title><addtitle>Chinese Journal of Polymer Science</addtitle><description>The dependence of measured viscosity on NaCl concentration (0.1 to 3.0M), pH (range of 2—13) and cadoxen composition wcad (from 2% to 100%) for the lacquer polysaccharide in NaCl/cadoxen/H2O mixture containing HCl or without were obtained. All the viscosity exponents γin the Mark-Houwink equations under three different solvent condition arc close to 0.5. The wcad dependence of reduced viscosity ηsp/c confirms the single strand chain of the polysaccharide. 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All the viscosity exponents γin the Mark-Houwink equations under three different solvent condition arc close to 0.5. The wcad dependence of reduced viscosity ηsp/c confirms the single strand chain of the polysaccharide. As the γvalues close to 0.5 and values of unperturbed dimension &lt;S2&gt;θ/M and [η] much smaller than those for usual linear polymers, these facts suggest that the polysaccharide chains in the aqueous solutions should be dense random coil owing to the highly branched structure.</abstract></addata></record> |
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subjects | Aqueous cadoxen Intrinsic Lacquer Polysaccharidc solution viscosity |
title | VISCOSITY BEHAVIOR OF LACQUER POLYSACCHARIDE IN AQUEOUS SOLUTION |
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