VISCOSITY BEHAVIOR OF LACQUER POLYSACCHARIDE IN AQUEOUS SOLUTION

The dependence of measured viscosity on NaCl concentration (0.1 to 3.0M), pH (range of 2—13) and cadoxen composition wcad (from 2% to 100%) for the lacquer polysaccharide in NaCl/cadoxen/H2O mixture containing HCl or without were obtained. All the viscosity exponents γin the Mark-Houwink equations u...

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Veröffentlicht in:高分子科学:英文版 1991 (1), p.94-100
1. Verfasser: 邱星屏 张俐娜 杜予民 钱保功
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description The dependence of measured viscosity on NaCl concentration (0.1 to 3.0M), pH (range of 2—13) and cadoxen composition wcad (from 2% to 100%) for the lacquer polysaccharide in NaCl/cadoxen/H2O mixture containing HCl or without were obtained. All the viscosity exponents γin the Mark-Houwink equations under three different solvent condition arc close to 0.5. The wcad dependence of reduced viscosity ηsp/c confirms the single strand chain of the polysaccharide. As the γvalues close to 0.5 and values of unperturbed dimension <S2>θ/M and [η] much smaller than those for usual linear polymers, these facts suggest that the polysaccharide chains in the aqueous solutions should be dense random coil owing to the highly branched structure.
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language eng
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source Alma/SFX Local Collection
subjects Aqueous
cadoxen
Intrinsic
Lacquer
Polysaccharidc
solution
viscosity
title VISCOSITY BEHAVIOR OF LACQUER POLYSACCHARIDE IN AQUEOUS SOLUTION
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