Photochemical Studies on Aqueous Carboplatin
The photochemical products,quantum yields and mechanisms of aqueous Carboplatin havebeen studied at 313 and 254 nm irradiation.Excitation in the ligand field bands 1A1→1A2 and 1A1→1E leads tosubstitution reactions,giving diaquodiammineplatinum and tetraaquoplatinum.And then these complexesundergo th...
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| Veröffentlicht in: | 中国科学：化学英文版 1994 (7), p.799-806 |
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| container_title | 中国科学：化学英文版 |
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| creator | 刘伟平 杨懿昆 阙振寰 熊惠周 |
| description | The photochemical products,quantum yields and mechanisms of aqueous Carboplatin havebeen studied at 313 and 254 nm irradiation.Excitation in the ligand field bands 1A1→1A2 and 1A1→1E leads tosubstitution reactions,giving diaquodiammineplatinum and tetraaquoplatinum.And then these complexesundergo thermally hydrolysis and polymerization producing polymeric hydroxo-bridged complexes.Oxygen isnot involved in the reactions.Excitation in the charge-transfer band 1A1→1A2u results in redox reaction.Metallic platinum and diaquodiammineplatinum are formed,respectively,in the absence and the presence ofoxygen. |
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| identifier | ISSN: 1674-7291 |
| ispartof | 中国科学：化学英文版, 1994 (7), p.799-806 |
| issn | 1674-7291 1869-1870 |
| language | eng |
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| source | Alma/SFX Local Collection |
| subjects | anticancer Carboplatin complex photochemistry |
| title | Photochemical Studies on Aqueous Carboplatin |
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