Isothermal corrosion (γ'+γ) Ni3Al alloy in liquid zinc

The isothermal corrosion testing and microscopic examination of Ni3Al alloy in liquid zinc containing small amounts of aluminum (mass fraction less than 0.2%) at 450℃ were carried out. The results show that the controlling mechanism of the dissolution reaction is diffusion through a boundary layer i...

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Veröffentlicht in:Transactions of Nonferrous Metals Society of China 2006, Vol.16 (A02), p.206-210
1. Verfasser: 王文俊 林均品 王艳丽 陈国良
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description The isothermal corrosion testing and microscopic examination of Ni3Al alloy in liquid zinc containing small amounts of aluminum (mass fraction less than 0.2%) at 450℃ were carried out. The results show that the controlling mechanism of the dissolution reaction is diffusion through a boundary layer into liquid zinc. For two-phase alloy, Ni3Al alloy (γ'+γ), the interface between dissolving solid and liquid remains remarkably planar and the difference in dissolution of the two adjacent phases (γ'+γ) can not be experimentally observed. The boundaries between y' phase and y phase play no perceptible role in the dissolution of Ni3Al alloy in liquid zinc. The X-ray diffi'action spectra of the diffusion layer confirm the presence of Ni5Zn21. The corrosion rate of the Ni3Al alloy in molten zinc was calculated to be approximately 2.6×10^-3 g/(cm^2·h), therefore the liquid zinc corrosion resistance of Ni3Al alloy is very weak.
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subjects Ni3Al合金
液锌腐蚀
热浸镀锌
等温腐蚀
金属间化合物
title Isothermal corrosion (γ'+γ) Ni3Al alloy in liquid zinc
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