Cooperative Chiral Order in Copolymers of Chiral and Achiral Units

Phys. Rev. E 55, 1728 (1997) Polyisocyanates can be synthesized with chiral and achiral pendant groups distributed randomly along the chains. The overall chiral order, measured by optical activity, is strongly cooperative and depends sensitively on the concentration of chiral pendant groups. To expl...

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Hauptverfasser:	Selinger, J. V, Selinger, R. L. B
Format:	Artikel
Sprache:	eng
Schlagworte:	Physics - Disordered Systems and Neural Networks Physics - Materials Science Physics - Mesoscale and Nanoscale Physics Physics - Other Condensed Matter Physics - Quantum Gases Physics - Soft Condensed Matter Physics - Statistical Mechanics Physics - Strongly Correlated Electrons Physics - Superconductivity
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creator	Selinger, J. V Selinger, R. L. B
description	Phys. Rev. E 55, 1728 (1997) Polyisocyanates can be synthesized with chiral and achiral pendant groups distributed randomly along the chains. The overall chiral order, measured by optical activity, is strongly cooperative and depends sensitively on the concentration of chiral pendant groups. To explain this cooperative chiral order theoretically, we map the random copolymer onto the one-dimensional random-field Ising model. We show that the optical activity as a function of composition is well-described by the predictions of this theory.
doi_str_mv	10.48550/arxiv.cond-mat/9608108
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subjects	Physics - Disordered Systems and Neural Networks Physics - Materials Science Physics - Mesoscale and Nanoscale Physics Physics - Other Condensed Matter Physics - Quantum Gases Physics - Soft Condensed Matter Physics - Statistical Mechanics Physics - Strongly Correlated Electrons Physics - Superconductivity
title	Cooperative Chiral Order in Copolymers of Chiral and Achiral Units
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