Double Layer-Interlocked Crystals of Nitrogen-Rich Compounds under Zero-Pressure Conditions
Stabilizing nitrogen-rich compound crystals under conventional conditions is a key issue in the development and application of high-energy density materials (HEDMs). Herein, a two-dimensional double-layer interlocked Li4(N5)2 nitrogen-rich compound crystals, in which the two N5 rings are locked to b...
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| creator | Gong, Zhen Liu, Baiqiang Yang, Xinrui Jing, Hongbo Xu, Ruiqi Wang, Zhigang |
| description | Stabilizing nitrogen-rich compound crystals under conventional conditions is
a key issue in the development and application of high-energy density materials
(HEDMs). Herein, a two-dimensional double-layer interlocked Li4(N5)2
nitrogen-rich compound crystals, in which the two N5 rings are locked to by
sharing four Li atoms, was found to maintain structural stability at zero
pressure conditions. Dynamics studies reliably confirm crystal stability below
250 K. Furthermore, the stability of Li4(N5)2 crystal mainly arises from the
ionic interaction between Li atoms and N5 rings, formed by the charge transfer
from Li atoms to N5 rings. This study highlights the feasibility of stabilizing
nitrogen-rich compound crystals under conventional conditions, paving the way
for atomic level advancements in HEDMs. |
| doi_str_mv | 10.48550/arxiv.2412.01497 |
| format | Article |
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a key issue in the development and application of high-energy density materials
(HEDMs). Herein, a two-dimensional double-layer interlocked Li4(N5)2
nitrogen-rich compound crystals, in which the two N5 rings are locked to by
sharing four Li atoms, was found to maintain structural stability at zero
pressure conditions. Dynamics studies reliably confirm crystal stability below
250 K. Furthermore, the stability of Li4(N5)2 crystal mainly arises from the
ionic interaction between Li atoms and N5 rings, formed by the charge transfer
from Li atoms to N5 rings. This study highlights the feasibility of stabilizing
nitrogen-rich compound crystals under conventional conditions, paving the way
for atomic level advancements in HEDMs.</description><identifier>DOI: 10.48550/arxiv.2412.01497</identifier><language>eng</language><subject>Physics - Computational Physics ; Physics - Materials Science ; Physics - Soft Condensed Matter</subject><creationdate>2024-12</creationdate><rights>http://creativecommons.org/licenses/by/4.0</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>228,230,780,885</link.rule.ids><linktorsrc>$$Uhttps://arxiv.org/abs/2412.01497$$EView_record_in_Cornell_University$$FView_record_in_$$GCornell_University$$Hfree_for_read</linktorsrc><backlink>$$Uhttps://doi.org/10.48550/arXiv.2412.01497$$DView paper in arXiv$$Hfree_for_read</backlink></links><search><creatorcontrib>Gong, Zhen</creatorcontrib><creatorcontrib>Liu, Baiqiang</creatorcontrib><creatorcontrib>Yang, Xinrui</creatorcontrib><creatorcontrib>Jing, Hongbo</creatorcontrib><creatorcontrib>Xu, Ruiqi</creatorcontrib><creatorcontrib>Wang, Zhigang</creatorcontrib><title>Double Layer-Interlocked Crystals of Nitrogen-Rich Compounds under Zero-Pressure Conditions</title><description>Stabilizing nitrogen-rich compound crystals under conventional conditions is
a key issue in the development and application of high-energy density materials
(HEDMs). Herein, a two-dimensional double-layer interlocked Li4(N5)2
nitrogen-rich compound crystals, in which the two N5 rings are locked to by
sharing four Li atoms, was found to maintain structural stability at zero
pressure conditions. Dynamics studies reliably confirm crystal stability below
250 K. Furthermore, the stability of Li4(N5)2 crystal mainly arises from the
ionic interaction between Li atoms and N5 rings, formed by the charge transfer
from Li atoms to N5 rings. This study highlights the feasibility of stabilizing
nitrogen-rich compound crystals under conventional conditions, paving the way
for atomic level advancements in HEDMs.</description><subject>Physics - Computational Physics</subject><subject>Physics - Materials Science</subject><subject>Physics - Soft Condensed Matter</subject><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>GOX</sourceid><recordid>eNqFjrEOgjAURbs4GPUDnOwPFAEh6owaTYwxxkmHpsJDG6GPvBYjfy8Sd5d7h3tycxgbB74XLeLYnyp665cXRkHo-UG0nPfZdYX1rQC-Vw2Q2BkHVGD6hIwn1FinCssx5wftCO9gxEmnD55gWWFtMsvbAOIXIBRHAmtrgnY1mXYajR2yXt4ewOjXAzbZrM_JVnQasiJdKmrkV0d2OrP_xAckq0Eb</recordid><startdate>20241202</startdate><enddate>20241202</enddate><creator>Gong, Zhen</creator><creator>Liu, Baiqiang</creator><creator>Yang, Xinrui</creator><creator>Jing, Hongbo</creator><creator>Xu, Ruiqi</creator><creator>Wang, Zhigang</creator><scope>GOX</scope></search><sort><creationdate>20241202</creationdate><title>Double Layer-Interlocked Crystals of Nitrogen-Rich Compounds under Zero-Pressure Conditions</title><author>Gong, Zhen ; Liu, Baiqiang ; Yang, Xinrui ; Jing, Hongbo ; Xu, Ruiqi ; Wang, Zhigang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-arxiv_primary_2412_014973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Physics - Computational Physics</topic><topic>Physics - Materials Science</topic><topic>Physics - Soft Condensed Matter</topic><toplevel>online_resources</toplevel><creatorcontrib>Gong, Zhen</creatorcontrib><creatorcontrib>Liu, Baiqiang</creatorcontrib><creatorcontrib>Yang, Xinrui</creatorcontrib><creatorcontrib>Jing, Hongbo</creatorcontrib><creatorcontrib>Xu, Ruiqi</creatorcontrib><creatorcontrib>Wang, Zhigang</creatorcontrib><collection>arXiv.org</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Gong, Zhen</au><au>Liu, Baiqiang</au><au>Yang, Xinrui</au><au>Jing, Hongbo</au><au>Xu, Ruiqi</au><au>Wang, Zhigang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Double Layer-Interlocked Crystals of Nitrogen-Rich Compounds under Zero-Pressure Conditions</atitle><date>2024-12-02</date><risdate>2024</risdate><abstract>Stabilizing nitrogen-rich compound crystals under conventional conditions is
a key issue in the development and application of high-energy density materials
(HEDMs). Herein, a two-dimensional double-layer interlocked Li4(N5)2
nitrogen-rich compound crystals, in which the two N5 rings are locked to by
sharing four Li atoms, was found to maintain structural stability at zero
pressure conditions. Dynamics studies reliably confirm crystal stability below
250 K. Furthermore, the stability of Li4(N5)2 crystal mainly arises from the
ionic interaction between Li atoms and N5 rings, formed by the charge transfer
from Li atoms to N5 rings. This study highlights the feasibility of stabilizing
nitrogen-rich compound crystals under conventional conditions, paving the way
for atomic level advancements in HEDMs.</abstract><doi>10.48550/arxiv.2412.01497</doi><oa>free_for_read</oa></addata></record> |
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| subjects | Physics - Computational Physics Physics - Materials Science Physics - Soft Condensed Matter |
| title | Double Layer-Interlocked Crystals of Nitrogen-Rich Compounds under Zero-Pressure Conditions |
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