Apparent fractionation of isotopes in moderately cooled argon
The fractionation of isotopes of natural Ar near the condensation (Tc) and freezing point has been studied using mass spectrometry (MS), numerical modeling and density functional theory. The heat of formation of 0.30, 0.52 and 0.70 kJ per Ar atom of the clusters Ar2, Ar3 and Ar4, respectively, shows...
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