A ferrotoroidic candidate with well-separated spin chains

The search of novel quasi one-dimensional (1D) materials is one of the important aspects in the field of material science. Toroidal moment, the order parameter of ferrotoroidic order, can be generated by a head-to-tail configuration of magnetic moment. It has been theoretically proposed that one-dim...

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Hauptverfasser: Zhang, Jun, Wang, Xiancheng, Zhou, Long, Liu, Gangxiu, Adroja, Devashibhai T, da Silva, Ivan, Demmel, Franz, Khalyavin, Dmitry, Sannigrahi, Jhuma, Nair, Hari S, Duan, Lei, Zhao, Jianfa, Deng, Zeng, Yu, Runze, Shen, Xi, Yu, Richeng, Zhao, Hui, Zhao, Jimin, Long, Youwen, Hu, Zhiwei, Lin, Hong-Ji, Chan, Ting-Shan, Chen, Chien-Te, Wu, Wei, Jin, Changqing
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creator Zhang, Jun
Wang, Xiancheng
Zhou, Long
Liu, Gangxiu
Adroja, Devashibhai T
da Silva, Ivan
Demmel, Franz
Khalyavin, Dmitry
Sannigrahi, Jhuma
Nair, Hari S
Duan, Lei
Zhao, Jianfa
Deng, Zeng
Yu, Runze
Shen, Xi
Yu, Richeng
Zhao, Hui
Zhao, Jimin
Long, Youwen
Hu, Zhiwei
Lin, Hong-Ji
Chan, Ting-Shan
Chen, Chien-Te
Wu, Wei
Jin, Changqing
description The search of novel quasi one-dimensional (1D) materials is one of the important aspects in the field of material science. Toroidal moment, the order parameter of ferrotoroidic order, can be generated by a head-to-tail configuration of magnetic moment. It has been theoretically proposed that one-dimensional (1D) dimerized and antiferromagnetic-like spin chain hosts ferrotoroidicity and has the toroidal moment composed of only two antiparallel spins. Here, we report a ferrotoroidic candidate of Ba6Cr2S10 with such a theoretical model of spin chain. The structure consists of unique dimerized face-sharing CrS6 octahedral chains along the c axis. An antiferromagnetic-like ordering at ~10 K breaks both space- and time-reversal symmetries and the magnetic point group of mm'2' allows three ferroic orders in Ba6Cr2S10: (anti)ferromagnetic, ferroelectric and ferrotoroidic orders. Our investigation reveals that Ba6Cr2S10 is a rare ferrotoroidic candidate with quasi 1D spin chain, which can be considered as a starting point for the further exploration of the physics and applications of ferrotoroidicity.
doi_str_mv 10.48550/arxiv.2201.08601
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Toroidal moment, the order parameter of ferrotoroidic order, can be generated by a head-to-tail configuration of magnetic moment. It has been theoretically proposed that one-dimensional (1D) dimerized and antiferromagnetic-like spin chain hosts ferrotoroidicity and has the toroidal moment composed of only two antiparallel spins. Here, we report a ferrotoroidic candidate of Ba6Cr2S10 with such a theoretical model of spin chain. The structure consists of unique dimerized face-sharing CrS6 octahedral chains along the c axis. An antiferromagnetic-like ordering at ~10 K breaks both space- and time-reversal symmetries and the magnetic point group of mm'2' allows three ferroic orders in Ba6Cr2S10: (anti)ferromagnetic, ferroelectric and ferrotoroidic orders. 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Toroidal moment, the order parameter of ferrotoroidic order, can be generated by a head-to-tail configuration of magnetic moment. It has been theoretically proposed that one-dimensional (1D) dimerized and antiferromagnetic-like spin chain hosts ferrotoroidicity and has the toroidal moment composed of only two antiparallel spins. Here, we report a ferrotoroidic candidate of Ba6Cr2S10 with such a theoretical model of spin chain. The structure consists of unique dimerized face-sharing CrS6 octahedral chains along the c axis. An antiferromagnetic-like ordering at ~10 K breaks both space- and time-reversal symmetries and the magnetic point group of mm'2' allows three ferroic orders in Ba6Cr2S10: (anti)ferromagnetic, ferroelectric and ferrotoroidic orders. Our investigation reveals that Ba6Cr2S10 is a rare ferrotoroidic candidate with quasi 1D spin chain, which can be considered as a starting point for the further exploration of the physics and applications of ferrotoroidicity.</abstract><doi>10.48550/arxiv.2201.08601</doi><oa>free_for_read</oa></addata></record>
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title A ferrotoroidic candidate with well-separated spin chains
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