Quantifying Angular Correlations between the Atomic Lattice and Superlattice of Nanocrystals Assembled with Directional Linking
We show that the combination of X-ray scattering with a nanofocused beam and X-ray cross correlation analysis is an efficient means for the full structural characterization of mesocrystalline nanoparticle assemblies with a single experiment. We analyze several hundred diffraction patterns of individ...
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| creator | Zaluzhnyy, Ivan A Kurta, Ruslan P Alexander, Andre Gorobtsov, Oleg Y Rose, Max Skopintsev, Petr Besedin, Ilya Zozulya, Alexey V Sprung, Michael Schreiber, Frank Vartanyants, Ivan A Scheele, Marcus |
| description | We show that the combination of X-ray scattering with a nanofocused beam and X-ray cross correlation analysis is an efficient means for the full structural characterization of mesocrystalline nanoparticle assemblies with a single experiment. We analyze several hundred diffraction patterns of individual sample locations, i.e. individual grains, to obtain a meaningful statistical distribution of the superlattice and atomic lattice ordering. Simultaneous small- and wide-angle X-ray scattering of the same sample location allows us to determine the structure and orientation of the superlattice as well as the angular correlation of the first two Bragg peaks of the atomic lattices, their orientation with respect to the superlattice, and the average orientational misfit due to local structural disorder. This experiment is particularly advantageous for synthetic mesocrystals made by the simultaneous self-assembly of colloidal nanocrystals and surface-functionalization with conductive ligands. While the structural characterization of such materials has been challenging so far, the present method now allows correlating mesocrystalline structure with optoelectronic properties. |
| doi_str_mv | 10.48550/arxiv.1702.05742 |
| format | Article |
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We analyze several hundred diffraction patterns of individual sample locations, i.e. individual grains, to obtain a meaningful statistical distribution of the superlattice and atomic lattice ordering. Simultaneous small- and wide-angle X-ray scattering of the same sample location allows us to determine the structure and orientation of the superlattice as well as the angular correlation of the first two Bragg peaks of the atomic lattices, their orientation with respect to the superlattice, and the average orientational misfit due to local structural disorder. This experiment is particularly advantageous for synthetic mesocrystals made by the simultaneous self-assembly of colloidal nanocrystals and surface-functionalization with conductive ligands. 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We analyze several hundred diffraction patterns of individual sample locations, i.e. individual grains, to obtain a meaningful statistical distribution of the superlattice and atomic lattice ordering. Simultaneous small- and wide-angle X-ray scattering of the same sample location allows us to determine the structure and orientation of the superlattice as well as the angular correlation of the first two Bragg peaks of the atomic lattices, their orientation with respect to the superlattice, and the average orientational misfit due to local structural disorder. This experiment is particularly advantageous for synthetic mesocrystals made by the simultaneous self-assembly of colloidal nanocrystals and surface-functionalization with conductive ligands. While the structural characterization of such materials has been challenging so far, the present method now allows correlating mesocrystalline structure with optoelectronic properties.</description><subject>Angular correlation</subject><subject>Correlation analysis</subject><subject>Cross correlation</subject><subject>Diffraction patterns</subject><subject>Lattices</subject><subject>Nanocrystals</subject><subject>Nanoparticles</subject><subject>Optoelectronics</subject><subject>Physics - Materials Science</subject><subject>Physics - Mesoscale and Nanoscale Physics</subject><subject>Self-assembly</subject><subject>Structural analysis</subject><subject>Superlattices</subject><subject>X-ray scattering</subject><issn>2331-8422</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><sourceid>GOX</sourceid><recordid>eNotkEtPwzAQhC0kJKrSH8AJS5xT1q8kPUblKUUgRO-Rk2xal9QptkPpib9O-jitdvbT7GgIuWEwlalScK_dr_mZsgT4FFQi-QUZcSFYlErOr8jE-zUA8DjhSokR-fvotQ2m2Ru7pJld9q12dN45h60OprOelhh2iJaGFdIsdBtT0VyHYCqk2tb0s9-ia89C19A3bbvK7X3QraeZ97gpW6zpzoQVfTAOq4Orbmlu7Nfw85pcNgOJk_Mck8XT42L-EuXvz6_zLI-04jLiSSlBAgOGWDKGSSmg4sOFMQ2qjlMBqmm0ZLEqOYBu6joe1LKq8LCgGJPbk-2xnWLrzEa7fXFoqTi2NBB3J2Lruu8efSjWXe-GpL7gkKjZTKRMin8-Y2zs</recordid><startdate>20170219</startdate><enddate>20170219</enddate><creator>Zaluzhnyy, Ivan A</creator><creator>Kurta, Ruslan P</creator><creator>Alexander, Andre</creator><creator>Gorobtsov, Oleg Y</creator><creator>Rose, Max</creator><creator>Skopintsev, Petr</creator><creator>Besedin, Ilya</creator><creator>Zozulya, Alexey V</creator><creator>Sprung, Michael</creator><creator>Schreiber, Frank</creator><creator>Vartanyants, Ivan A</creator><creator>Scheele, Marcus</creator><general>Cornell University Library, arXiv.org</general><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>GOX</scope></search><sort><creationdate>20170219</creationdate><title>Quantifying Angular Correlations between the Atomic Lattice and Superlattice of Nanocrystals Assembled with Directional Linking</title><author>Zaluzhnyy, Ivan A ; Kurta, Ruslan P ; Alexander, Andre ; Gorobtsov, Oleg Y ; Rose, Max ; Skopintsev, Petr ; Besedin, Ilya ; Zozulya, Alexey V ; Sprung, Michael ; Schreiber, Frank ; Vartanyants, Ivan A ; Scheele, Marcus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a524-27b4040101eeb11e7b30c252411a05d68305ffa4165b200afdd6d68bcce0afde3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Angular correlation</topic><topic>Correlation analysis</topic><topic>Cross correlation</topic><topic>Diffraction patterns</topic><topic>Lattices</topic><topic>Nanocrystals</topic><topic>Nanoparticles</topic><topic>Optoelectronics</topic><topic>Physics - Materials Science</topic><topic>Physics - Mesoscale and Nanoscale Physics</topic><topic>Self-assembly</topic><topic>Structural analysis</topic><topic>Superlattices</topic><topic>X-ray scattering</topic><toplevel>online_resources</toplevel><creatorcontrib>Zaluzhnyy, Ivan A</creatorcontrib><creatorcontrib>Kurta, Ruslan P</creatorcontrib><creatorcontrib>Alexander, Andre</creatorcontrib><creatorcontrib>Gorobtsov, Oleg Y</creatorcontrib><creatorcontrib>Rose, Max</creatorcontrib><creatorcontrib>Skopintsev, Petr</creatorcontrib><creatorcontrib>Besedin, Ilya</creatorcontrib><creatorcontrib>Zozulya, Alexey V</creatorcontrib><creatorcontrib>Sprung, Michael</creatorcontrib><creatorcontrib>Schreiber, Frank</creatorcontrib><creatorcontrib>Vartanyants, Ivan A</creatorcontrib><creatorcontrib>Scheele, Marcus</creatorcontrib><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>arXiv.org</collection><jtitle>arXiv.org</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zaluzhnyy, Ivan A</au><au>Kurta, Ruslan P</au><au>Alexander, Andre</au><au>Gorobtsov, Oleg Y</au><au>Rose, Max</au><au>Skopintsev, Petr</au><au>Besedin, Ilya</au><au>Zozulya, Alexey V</au><au>Sprung, Michael</au><au>Schreiber, Frank</au><au>Vartanyants, Ivan A</au><au>Scheele, Marcus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quantifying Angular Correlations between the Atomic Lattice and Superlattice of Nanocrystals Assembled with Directional Linking</atitle><jtitle>arXiv.org</jtitle><date>2017-02-19</date><risdate>2017</risdate><eissn>2331-8422</eissn><abstract>We show that the combination of X-ray scattering with a nanofocused beam and X-ray cross correlation analysis is an efficient means for the full structural characterization of mesocrystalline nanoparticle assemblies with a single experiment. 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| subjects | Angular correlation Correlation analysis Cross correlation Diffraction patterns Lattices Nanocrystals Nanoparticles Optoelectronics Physics - Materials Science Physics - Mesoscale and Nanoscale Physics Self-assembly Structural analysis Superlattices X-ray scattering |
| title | Quantifying Angular Correlations between the Atomic Lattice and Superlattice of Nanocrystals Assembled with Directional Linking |
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