Observing magnetic anisotropy in electronic transport through individual single-molecule magnets
We review different electron transport methods to probe the magnetic properties, such as the magnetic anisotropy, of an individual Fe4 SMM. The different approaches comprise first and higher order transport through the molecule. Gate spectroscopy, focusing on the charge degeneracy-point, is presente...
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description | We review different electron transport methods to probe the magnetic properties, such as the magnetic anisotropy, of an individual Fe4 SMM. The different approaches comprise first and higher order transport through the molecule. Gate spectroscopy, focusing on the charge degeneracy-point, is presented as a robust technique to quantify the longitudinal magnetic anisotropy of the SMM in different redox states. We provide statistics showing the robustness and reproducibility of the different methods. In addition, conductance measurements typically show high-energy excited states well beyond the ground spin multiplet of SMM. Some of these excitations have their origin in excited spin multiplets, others in vibrational modes of the molecule. The interplay between vibrations, charge and spin may yield a new approach for spin control. |
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The different approaches comprise first and higher order transport through the molecule. Gate spectroscopy, focusing on the charge degeneracy-point, is presented as a robust technique to quantify the longitudinal magnetic anisotropy of the SMM in different redox states. We provide statistics showing the robustness and reproducibility of the different methods. In addition, conductance measurements typically show high-energy excited states well beyond the ground spin multiplet of SMM. Some of these excitations have their origin in excited spin multiplets, others in vibrational modes of the molecule. 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The interplay between vibrations, charge and spin may yield a new approach for spin control.</description><subject>Anisotropy</subject><subject>Electron transport</subject><subject>Magnetic anisotropy</subject><subject>Magnetic properties</subject><subject>Magnets</subject><subject>Measurement methods</subject><subject>Physics - Mesoscale and Nanoscale Physics</subject><subject>Reproducibility</subject><subject>Resistance</subject><issn>2331-8422</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GOX</sourceid><recordid>eNotkEtrwzAQhEWh0JDmB_RUQ89O9ZZ8LKGPQCCX3F3Zlh0FW3Il2TT_vmqS07I7H8POAPCE4JpKxuCr8r9mXiMO-RpiJvAdWGBCUC4pxg9gFcIJQoi5wIyRBfjeV0H72dguG1RndTR1pqwJLno3njNjM93rOi02CdErG0bnYxaP3k3dMemNmU0zqT4LyaPX-eASP_X6ZhcewX2r-qBXt7kEh4_3w-Yr3-0_t5u3Xa4Y5jkXTGtKad1oUguGUKUqAkk6p0ySKtESKXXBRYNZRSUqMCtaVRekxbytISJL8Hy1vcQvR28G5c_lfw3lpYZEvFyJ0bufSYdYntzkbfqpxFAUkkkoOPkDf-5how</recordid><startdate>20160608</startdate><enddate>20160608</enddate><creator>Burzurí, E</creator><creator>Gaudenzi, R</creator><creator>H S J van der Zant</creator><general>Cornell University Library, arXiv.org</general><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>GOX</scope></search><sort><creationdate>20160608</creationdate><title>Observing magnetic anisotropy in electronic transport through individual single-molecule magnets</title><author>Burzurí, E ; Gaudenzi, R ; H S J van der Zant</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a526-675ee444cde3c7511bab30367585584a7f388e967d25b4819259fac93f26fc013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Anisotropy</topic><topic>Electron transport</topic><topic>Magnetic anisotropy</topic><topic>Magnetic properties</topic><topic>Magnets</topic><topic>Measurement methods</topic><topic>Physics - Mesoscale and Nanoscale Physics</topic><topic>Reproducibility</topic><topic>Resistance</topic><toplevel>online_resources</toplevel><creatorcontrib>Burzurí, E</creatorcontrib><creatorcontrib>Gaudenzi, R</creatorcontrib><creatorcontrib>H S J van der Zant</creatorcontrib><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>arXiv.org</collection><jtitle>arXiv.org</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Burzurí, E</au><au>Gaudenzi, R</au><au>H S J van der Zant</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Observing magnetic anisotropy in electronic transport through individual single-molecule magnets</atitle><jtitle>arXiv.org</jtitle><date>2016-06-08</date><risdate>2016</risdate><eissn>2331-8422</eissn><abstract>We review different electron transport methods to probe the magnetic properties, such as the magnetic anisotropy, of an individual Fe4 SMM. 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subjects | Anisotropy Electron transport Magnetic anisotropy Magnetic properties Magnets Measurement methods Physics - Mesoscale and Nanoscale Physics Reproducibility Resistance |
title | Observing magnetic anisotropy in electronic transport through individual single-molecule magnets |
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