Electronic isotope shift factors for the Cu $4s \; ^2S_{1/2} - 4p \; ^2P^o_{3/2}$ line
State-of-the-art relativistic multiconfiguration Dirac-Hartree-Fock calculations have been performed to evaluate the electronic field and mass isotope shift factors of the Cu~I resonance line at $\lambda = 324.8$~nm. A linear correlation between the mass factors and the transition energy is found fo...
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Zusammenfassung: | State-of-the-art relativistic multiconfiguration Dirac-Hartree-Fock
calculations have been performed to evaluate the electronic field and mass
isotope shift factors of the Cu~I resonance line at $\lambda = 324.8$~nm. A
linear correlation between the mass factors and the transition energy is found
for elaborate correlation models, allowing extrapolation to the observed
frequency limit. The relativistic corrections to the recoil operator reduces
the transition mass factor by 5~\%. |
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DOI: | 10.48550/arxiv.1602.06574 |