Effect of Low-Damage Inductively Coupled Plasma on Shallow NV Centers in Diamond

Near-surface nitrogen-vacancy ({NV}) centers in diamond have been successfully employed as atomic-sized magnetic field sensors for external spins over the last years. A key challenge is still to develop a method to bring NV centers at nanometer proximity to the diamond surface while preserving their...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:arXiv.org 2015-07
Hauptverfasser: de Oliveira, Felipe Fávaro, S Ali Momenzadeh, Wang, Ya, Konuma, Mitsuharu, Markham, Matthew, Edmonds, Andrew M, Denisenko, Andrej, Wrachtrup, Jörg
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page
container_title arXiv.org
container_volume
creator de Oliveira, Felipe Fávaro
S Ali Momenzadeh
Wang, Ya
Konuma, Mitsuharu
Markham, Matthew
Edmonds, Andrew M
Denisenko, Andrej
Wrachtrup, Jörg
description Near-surface nitrogen-vacancy ({NV}) centers in diamond have been successfully employed as atomic-sized magnetic field sensors for external spins over the last years. A key challenge is still to develop a method to bring NV centers at nanometer proximity to the diamond surface while preserving their optical and spin properties. To that aim we present a method of controlled diamond etching with nanometric precision using an oxygen inductively coupled plasma (ICP) process. Importantly, no traces of plasma-induced damages to the etched surface could be detected by X-ray photoelectron spectroscopy (XPS) and confocal photoluminescence microscopy techniques. In addition, by profiling the depth of NV centers created by 5.0 keV of nitrogen implantation energy, no plasma-induced quenching in their fluorescence could be observed. Moreover, the developed etching process allowed even the channeling tail in their depth distribution to be resolved. Furthermore, treating a 12C isotopically purified diamond revealed a threefold increase in T2 times for NV centers with
doi_str_mv 10.48550/arxiv.1507.00890
format Article
fullrecord <record><control><sourceid>proquest_arxiv</sourceid><recordid>TN_cdi_arxiv_primary_1507_00890</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2083243895</sourcerecordid><originalsourceid>FETCH-LOGICAL-a525-a4d51dedbf4f854d4607e453c2d5700b58ac7213ea195c4b55924c8928d453373</originalsourceid><addsrcrecordid>eNotj81Kw0AURgdBsNQ-gCsHXKfezMxtJktJqy0ELVjchpvMRFOSTMxPa9_e2Lr6NoePcxi782GuNCI8UvtTHOY-QjAH0CFcsYmQ0ve0EuKGzbpuDwBiEQhEOWHbVZ7brOcu57E7ekuq6NPyTW2GrC8OtjzxyA1NaQ3fltRVxF3N37-oLN2Rv37wyNa9bTte1HxZUOVqc8uucyo7O_vfKds9r3bR2ovfXjbRU-wRCvRIGfSNNWmuco3KqAUEVqHMhMEAIEVNWSB8ackPMVMpYihUpkOhzUjJQE7Z_eX2nJs0bVFRe0r-spNz9kg8XIimdd-D7fpk74a2Hp0SAVoKJXWI8hczAVjI</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2083243895</pqid></control><display><type>article</type><title>Effect of Low-Damage Inductively Coupled Plasma on Shallow NV Centers in Diamond</title><source>arXiv.org</source><source>Open Access: Freely Accessible Journals by multiple vendors</source><creator>de Oliveira, Felipe Fávaro ; S Ali Momenzadeh ; Wang, Ya ; Konuma, Mitsuharu ; Markham, Matthew ; Edmonds, Andrew M ; Denisenko, Andrej ; Wrachtrup, Jörg</creator><creatorcontrib>de Oliveira, Felipe Fávaro ; S Ali Momenzadeh ; Wang, Ya ; Konuma, Mitsuharu ; Markham, Matthew ; Edmonds, Andrew M ; Denisenko, Andrej ; Wrachtrup, Jörg</creatorcontrib><description>Near-surface nitrogen-vacancy ({NV}) centers in diamond have been successfully employed as atomic-sized magnetic field sensors for external spins over the last years. A key challenge is still to develop a method to bring NV centers at nanometer proximity to the diamond surface while preserving their optical and spin properties. To that aim we present a method of controlled diamond etching with nanometric precision using an oxygen inductively coupled plasma (ICP) process. Importantly, no traces of plasma-induced damages to the etched surface could be detected by X-ray photoelectron spectroscopy (XPS) and confocal photoluminescence microscopy techniques. In addition, by profiling the depth of NV centers created by 5.0 keV of nitrogen implantation energy, no plasma-induced quenching in their fluorescence could be observed. Moreover, the developed etching process allowed even the channeling tail in their depth distribution to be resolved. Furthermore, treating a 12C isotopically purified diamond revealed a threefold increase in T2 times for NV centers with &lt;4 nm of depth (measured by NMR signal from protons at the diamond surface) in comparison to the initial oxygen-terminated surface.</description><identifier>EISSN: 2331-8422</identifier><identifier>DOI: 10.48550/arxiv.1507.00890</identifier><language>eng</language><publisher>Ithaca: Cornell University Library, arXiv.org</publisher><subject>Channeling ; Diamonds ; Etching ; Fluorescence ; Implantation ; Inductively coupled plasma ; NMR ; Nuclear magnetic resonance ; Optical properties ; Photoelectrons ; Photoluminescence ; Physics - Materials Science ; Plasma etching ; X ray photoelectron spectroscopy</subject><ispartof>arXiv.org, 2015-07</ispartof><rights>2015. This work is published under http://arxiv.org/licenses/nonexclusive-distrib/1.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>http://arxiv.org/licenses/nonexclusive-distrib/1.0</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>228,230,776,780,881,27902</link.rule.ids><backlink>$$Uhttps://doi.org/10.48550/arXiv.1507.00890$$DView paper in arXiv$$Hfree_for_read</backlink><backlink>$$Uhttps://doi.org/10.1063/1.4929356$$DView published paper (Access to full text may be restricted)$$Hfree_for_read</backlink></links><search><creatorcontrib>de Oliveira, Felipe Fávaro</creatorcontrib><creatorcontrib>S Ali Momenzadeh</creatorcontrib><creatorcontrib>Wang, Ya</creatorcontrib><creatorcontrib>Konuma, Mitsuharu</creatorcontrib><creatorcontrib>Markham, Matthew</creatorcontrib><creatorcontrib>Edmonds, Andrew M</creatorcontrib><creatorcontrib>Denisenko, Andrej</creatorcontrib><creatorcontrib>Wrachtrup, Jörg</creatorcontrib><title>Effect of Low-Damage Inductively Coupled Plasma on Shallow NV Centers in Diamond</title><title>arXiv.org</title><description>Near-surface nitrogen-vacancy ({NV}) centers in diamond have been successfully employed as atomic-sized magnetic field sensors for external spins over the last years. A key challenge is still to develop a method to bring NV centers at nanometer proximity to the diamond surface while preserving their optical and spin properties. To that aim we present a method of controlled diamond etching with nanometric precision using an oxygen inductively coupled plasma (ICP) process. Importantly, no traces of plasma-induced damages to the etched surface could be detected by X-ray photoelectron spectroscopy (XPS) and confocal photoluminescence microscopy techniques. In addition, by profiling the depth of NV centers created by 5.0 keV of nitrogen implantation energy, no plasma-induced quenching in their fluorescence could be observed. Moreover, the developed etching process allowed even the channeling tail in their depth distribution to be resolved. Furthermore, treating a 12C isotopically purified diamond revealed a threefold increase in T2 times for NV centers with &lt;4 nm of depth (measured by NMR signal from protons at the diamond surface) in comparison to the initial oxygen-terminated surface.</description><subject>Channeling</subject><subject>Diamonds</subject><subject>Etching</subject><subject>Fluorescence</subject><subject>Implantation</subject><subject>Inductively coupled plasma</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical properties</subject><subject>Photoelectrons</subject><subject>Photoluminescence</subject><subject>Physics - Materials Science</subject><subject>Plasma etching</subject><subject>X ray photoelectron spectroscopy</subject><issn>2331-8422</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><sourceid>GOX</sourceid><recordid>eNotj81Kw0AURgdBsNQ-gCsHXKfezMxtJktJqy0ELVjchpvMRFOSTMxPa9_e2Lr6NoePcxi782GuNCI8UvtTHOY-QjAH0CFcsYmQ0ve0EuKGzbpuDwBiEQhEOWHbVZ7brOcu57E7ekuq6NPyTW2GrC8OtjzxyA1NaQ3fltRVxF3N37-oLN2Rv37wyNa9bTte1HxZUOVqc8uucyo7O_vfKds9r3bR2ovfXjbRU-wRCvRIGfSNNWmuco3KqAUEVqHMhMEAIEVNWSB8ackPMVMpYihUpkOhzUjJQE7Z_eX2nJs0bVFRe0r-spNz9kg8XIimdd-D7fpk74a2Hp0SAVoKJXWI8hczAVjI</recordid><startdate>20150703</startdate><enddate>20150703</enddate><creator>de Oliveira, Felipe Fávaro</creator><creator>S Ali Momenzadeh</creator><creator>Wang, Ya</creator><creator>Konuma, Mitsuharu</creator><creator>Markham, Matthew</creator><creator>Edmonds, Andrew M</creator><creator>Denisenko, Andrej</creator><creator>Wrachtrup, Jörg</creator><general>Cornell University Library, arXiv.org</general><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>GOX</scope></search><sort><creationdate>20150703</creationdate><title>Effect of Low-Damage Inductively Coupled Plasma on Shallow NV Centers in Diamond</title><author>de Oliveira, Felipe Fávaro ; S Ali Momenzadeh ; Wang, Ya ; Konuma, Mitsuharu ; Markham, Matthew ; Edmonds, Andrew M ; Denisenko, Andrej ; Wrachtrup, Jörg</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a525-a4d51dedbf4f854d4607e453c2d5700b58ac7213ea195c4b55924c8928d453373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Channeling</topic><topic>Diamonds</topic><topic>Etching</topic><topic>Fluorescence</topic><topic>Implantation</topic><topic>Inductively coupled plasma</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Optical properties</topic><topic>Photoelectrons</topic><topic>Photoluminescence</topic><topic>Physics - Materials Science</topic><topic>Plasma etching</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>online_resources</toplevel><creatorcontrib>de Oliveira, Felipe Fávaro</creatorcontrib><creatorcontrib>S Ali Momenzadeh</creatorcontrib><creatorcontrib>Wang, Ya</creatorcontrib><creatorcontrib>Konuma, Mitsuharu</creatorcontrib><creatorcontrib>Markham, Matthew</creatorcontrib><creatorcontrib>Edmonds, Andrew M</creatorcontrib><creatorcontrib>Denisenko, Andrej</creatorcontrib><creatorcontrib>Wrachtrup, Jörg</creatorcontrib><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>ProQuest Engineering Database</collection><collection>Publicly Available Content Database (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering collection</collection><collection>arXiv.org</collection><jtitle>arXiv.org</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Oliveira, Felipe Fávaro</au><au>S Ali Momenzadeh</au><au>Wang, Ya</au><au>Konuma, Mitsuharu</au><au>Markham, Matthew</au><au>Edmonds, Andrew M</au><au>Denisenko, Andrej</au><au>Wrachtrup, Jörg</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Low-Damage Inductively Coupled Plasma on Shallow NV Centers in Diamond</atitle><jtitle>arXiv.org</jtitle><date>2015-07-03</date><risdate>2015</risdate><eissn>2331-8422</eissn><abstract>Near-surface nitrogen-vacancy ({NV}) centers in diamond have been successfully employed as atomic-sized magnetic field sensors for external spins over the last years. A key challenge is still to develop a method to bring NV centers at nanometer proximity to the diamond surface while preserving their optical and spin properties. To that aim we present a method of controlled diamond etching with nanometric precision using an oxygen inductively coupled plasma (ICP) process. Importantly, no traces of plasma-induced damages to the etched surface could be detected by X-ray photoelectron spectroscopy (XPS) and confocal photoluminescence microscopy techniques. In addition, by profiling the depth of NV centers created by 5.0 keV of nitrogen implantation energy, no plasma-induced quenching in their fluorescence could be observed. Moreover, the developed etching process allowed even the channeling tail in their depth distribution to be resolved. Furthermore, treating a 12C isotopically purified diamond revealed a threefold increase in T2 times for NV centers with &lt;4 nm of depth (measured by NMR signal from protons at the diamond surface) in comparison to the initial oxygen-terminated surface.</abstract><cop>Ithaca</cop><pub>Cornell University Library, arXiv.org</pub><doi>10.48550/arxiv.1507.00890</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier EISSN: 2331-8422
ispartof arXiv.org, 2015-07
issn 2331-8422
language eng
recordid cdi_arxiv_primary_1507_00890
source arXiv.org; Open Access: Freely Accessible Journals by multiple vendors
subjects Channeling
Diamonds
Etching
Fluorescence
Implantation
Inductively coupled plasma
NMR
Nuclear magnetic resonance
Optical properties
Photoelectrons
Photoluminescence
Physics - Materials Science
Plasma etching
X ray photoelectron spectroscopy
title Effect of Low-Damage Inductively Coupled Plasma on Shallow NV Centers in Diamond
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T11%3A47%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_arxiv&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effect%20of%20Low-Damage%20Inductively%20Coupled%20Plasma%20on%20Shallow%20NV%20Centers%20in%20Diamond&rft.jtitle=arXiv.org&rft.au=de%20Oliveira,%20Felipe%20F%C3%A1varo&rft.date=2015-07-03&rft.eissn=2331-8422&rft_id=info:doi/10.48550/arxiv.1507.00890&rft_dat=%3Cproquest_arxiv%3E2083243895%3C/proquest_arxiv%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2083243895&rft_id=info:pmid/&rfr_iscdi=true