Entropy variation rate divided by temperature always decreases
For an isolated assembly that comprises a system and its surrounding reservoirs, the total entropy ($S_{a}$) always monotonically increases as time elapses. This phenomenon is known as the second law of thermodynamics ($S_{a}\geq0$). Here we analytically prove that, unlike the entropy itself, the en...
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creator | Shih, T. M Gao, Z. J Merlitz, H Rondoni, L Pagni, P. J Chen, Z |
description | For an isolated assembly that comprises a system and its surrounding
reservoirs, the total entropy ($S_{a}$) always monotonically increases as time
elapses. This phenomenon is known as the second law of thermodynamics
($S_{a}\geq0$). Here we analytically prove that, unlike the entropy itself, the
entropy variation rate ($B=dS_{a}/dt$) defies the monotonicity for multiple
reservoirs ($n\geq2$). In other words, there always exist minima. For example,
when a system is heated by two reservoirs from $T=300\,K$ initially to
$T=400\,K$ at the final steady state, $B$ decreases steadily first. Then
suddenly it turns around and starts to increases at $387\,K$ until it reaches
its steady-state value, exhibiting peculiar dipping behaviors. In addition, the
crux of our work is the proof that a newly-defined variable, $B/T$, always
decreases. Our proof involves the Newton's law of cooling, in which the heat
transfer coefficient is assumed to be constant. These theoretical macro-scale
findings are validated by numerical experiments using the Crank-Nicholson
method, and are illustrated with practical examples. They constitute an
alternative to the traditional second-law statement, and may provide useful
references for the future micro-scale entropy-related research. |
doi_str_mv | 10.48550/arxiv.1410.5195 |
format | Article |
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reservoirs, the total entropy ($S_{a}$) always monotonically increases as time
elapses. This phenomenon is known as the second law of thermodynamics
($S_{a}\geq0$). Here we analytically prove that, unlike the entropy itself, the
entropy variation rate ($B=dS_{a}/dt$) defies the monotonicity for multiple
reservoirs ($n\geq2$). In other words, there always exist minima. For example,
when a system is heated by two reservoirs from $T=300\,K$ initially to
$T=400\,K$ at the final steady state, $B$ decreases steadily first. Then
suddenly it turns around and starts to increases at $387\,K$ until it reaches
its steady-state value, exhibiting peculiar dipping behaviors. In addition, the
crux of our work is the proof that a newly-defined variable, $B/T$, always
decreases. Our proof involves the Newton's law of cooling, in which the heat
transfer coefficient is assumed to be constant. These theoretical macro-scale
findings are validated by numerical experiments using the Crank-Nicholson
method, and are illustrated with practical examples. They constitute an
alternative to the traditional second-law statement, and may provide useful
references for the future micro-scale entropy-related research.</description><identifier>DOI: 10.48550/arxiv.1410.5195</identifier><language>eng</language><subject>Physics - Computational Physics</subject><creationdate>2014-10</creationdate><rights>http://arxiv.org/licenses/nonexclusive-distrib/1.0</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>228,230,780,885</link.rule.ids><linktorsrc>$$Uhttps://arxiv.org/abs/1410.5195$$EView_record_in_Cornell_University$$FView_record_in_$$GCornell_University$$Hfree_for_read</linktorsrc><backlink>$$Uhttps://doi.org/10.48550/arXiv.1410.5195$$DView paper in arXiv$$Hfree_for_read</backlink></links><search><creatorcontrib>Shih, T. M</creatorcontrib><creatorcontrib>Gao, Z. J</creatorcontrib><creatorcontrib>Merlitz, H</creatorcontrib><creatorcontrib>Rondoni, L</creatorcontrib><creatorcontrib>Pagni, P. J</creatorcontrib><creatorcontrib>Chen, Z</creatorcontrib><title>Entropy variation rate divided by temperature always decreases</title><description>For an isolated assembly that comprises a system and its surrounding
reservoirs, the total entropy ($S_{a}$) always monotonically increases as time
elapses. This phenomenon is known as the second law of thermodynamics
($S_{a}\geq0$). Here we analytically prove that, unlike the entropy itself, the
entropy variation rate ($B=dS_{a}/dt$) defies the monotonicity for multiple
reservoirs ($n\geq2$). In other words, there always exist minima. For example,
when a system is heated by two reservoirs from $T=300\,K$ initially to
$T=400\,K$ at the final steady state, $B$ decreases steadily first. Then
suddenly it turns around and starts to increases at $387\,K$ until it reaches
its steady-state value, exhibiting peculiar dipping behaviors. In addition, the
crux of our work is the proof that a newly-defined variable, $B/T$, always
decreases. Our proof involves the Newton's law of cooling, in which the heat
transfer coefficient is assumed to be constant. These theoretical macro-scale
findings are validated by numerical experiments using the Crank-Nicholson
method, and are illustrated with practical examples. They constitute an
alternative to the traditional second-law statement, and may provide useful
references for the future micro-scale entropy-related research.</description><subject>Physics - Computational Physics</subject><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>GOX</sourceid><recordid>eNotj01rwkAQhvfioWjvPcn-gdidzI4mF6GItQXBi_cwm5nAgh9hk6bNv6_anl54Di_PY8wLuIUviNwrp584LMDfAEFJT2a9vfTp2o524BS5j9eLTdyrlThEUbFhtL2eW73Br6SWT988dla0TsqddjMzafjU6fP_Ts3xfXvcfGT7w-5z87bPeEmUNd6HhiQAikIuTN5pjiUQhxWhD75e1uIASVYkQI4LLAMhQ4Hkmtzh1Mz_bh_-VZvimdNY3Tuqewf-AmTAQsA</recordid><startdate>20141020</startdate><enddate>20141020</enddate><creator>Shih, T. M</creator><creator>Gao, Z. J</creator><creator>Merlitz, H</creator><creator>Rondoni, L</creator><creator>Pagni, P. J</creator><creator>Chen, Z</creator><scope>GOX</scope></search><sort><creationdate>20141020</creationdate><title>Entropy variation rate divided by temperature always decreases</title><author>Shih, T. M ; Gao, Z. J ; Merlitz, H ; Rondoni, L ; Pagni, P. J ; Chen, Z</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a655-f44bf5db13de12da540e23915ab7534b4c6cd0135d75d150a839b53a18350f203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Physics - Computational Physics</topic><toplevel>online_resources</toplevel><creatorcontrib>Shih, T. M</creatorcontrib><creatorcontrib>Gao, Z. J</creatorcontrib><creatorcontrib>Merlitz, H</creatorcontrib><creatorcontrib>Rondoni, L</creatorcontrib><creatorcontrib>Pagni, P. J</creatorcontrib><creatorcontrib>Chen, Z</creatorcontrib><collection>arXiv.org</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Shih, T. M</au><au>Gao, Z. J</au><au>Merlitz, H</au><au>Rondoni, L</au><au>Pagni, P. J</au><au>Chen, Z</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Entropy variation rate divided by temperature always decreases</atitle><date>2014-10-20</date><risdate>2014</risdate><abstract>For an isolated assembly that comprises a system and its surrounding
reservoirs, the total entropy ($S_{a}$) always monotonically increases as time
elapses. This phenomenon is known as the second law of thermodynamics
($S_{a}\geq0$). Here we analytically prove that, unlike the entropy itself, the
entropy variation rate ($B=dS_{a}/dt$) defies the monotonicity for multiple
reservoirs ($n\geq2$). In other words, there always exist minima. For example,
when a system is heated by two reservoirs from $T=300\,K$ initially to
$T=400\,K$ at the final steady state, $B$ decreases steadily first. Then
suddenly it turns around and starts to increases at $387\,K$ until it reaches
its steady-state value, exhibiting peculiar dipping behaviors. In addition, the
crux of our work is the proof that a newly-defined variable, $B/T$, always
decreases. Our proof involves the Newton's law of cooling, in which the heat
transfer coefficient is assumed to be constant. These theoretical macro-scale
findings are validated by numerical experiments using the Crank-Nicholson
method, and are illustrated with practical examples. They constitute an
alternative to the traditional second-law statement, and may provide useful
references for the future micro-scale entropy-related research.</abstract><doi>10.48550/arxiv.1410.5195</doi><oa>free_for_read</oa></addata></record> |
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title | Entropy variation rate divided by temperature always decreases |
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