Concentration dependence of the Flory-Huggins interaction parameter in aqueous solutions of capped PEO chains

The dependence on volume fraction \(\varphi\) of the Flory-Huggins \(\chi_{\mathrm{wp}}\left(\varphi\right)\) describing the free energy of mixing of polymers in water is obtained by exploiting the connection of \(\chi_{\mathrm{wp}}\left(\varphi\right)\) to the chemical potential of the water, for w...

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Veröffentlicht in:	arXiv.org 2014-10
Hauptverfasser:	Chaudhari, M I, Pratt, L R, Paulaitis, M E
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous solutions Chemical potential Dependence Free energy Interaction parameters Mathematical models Oligomers Organic chemistry Physics - Chemical Physics Physics - Soft Condensed Matter Thermodynamics Virial coefficients
Online-Zugang:	Volltext
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