Common effect of chemical and external pressures on the magnetic properties of RECoPO (RE = La, Pr)
We report a detailed investigation of RECoPO (RE = La, Pr) and LaCoAsO materials performed by means of muon spin spectroscopy. Zero-field measurements show that the electrons localized on the Pr\(^{3+}\) ions do not play any role in the static magnetic properties of the compounds. Magnetism at the l...
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creator | Prando, G Bonfà, P Profeta, G Khasanov, R Bernardini, F Mazzani, M Brüning, E M Pal, A Awana, V P S H -J Grafe Büchner, B De Renzi, R Carretta, P Sanna, S |
description | We report a detailed investigation of RECoPO (RE = La, Pr) and LaCoAsO materials performed by means of muon spin spectroscopy. Zero-field measurements show that the electrons localized on the Pr\(^{3+}\) ions do not play any role in the static magnetic properties of the compounds. Magnetism at the local level is indeed fully dominated by the weakly-itinerant ferromagnetism from the Co sublattice only. The increase of the chemical pressure triggered by the different ionic radii of La\(^{3+}\) and Pr\(^{3+}\), on the other hand, plays a crucial role in enhancing the value of the magnetic critical temperature and can be mimicked by the application of external hydrostatic pressure up to 24 kbar. A sharp discontinuity in the local magnetic field at the muon site in LaCoPO at around 5 kbar suggests a sizeable modification in the band structure of the material upon increasing pressure. This scenario is qualitatively supported by \emph{ab-initio} density-functional theory calculations. |
doi_str_mv | 10.48550/arxiv.1212.5087 |
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Zero-field measurements show that the electrons localized on the Pr\(^{3+}\) ions do not play any role in the static magnetic properties of the compounds. Magnetism at the local level is indeed fully dominated by the weakly-itinerant ferromagnetism from the Co sublattice only. The increase of the chemical pressure triggered by the different ionic radii of La\(^{3+}\) and Pr\(^{3+}\), on the other hand, plays a crucial role in enhancing the value of the magnetic critical temperature and can be mimicked by the application of external hydrostatic pressure up to 24 kbar. A sharp discontinuity in the local magnetic field at the muon site in LaCoPO at around 5 kbar suggests a sizeable modification in the band structure of the material upon increasing pressure. This scenario is qualitatively supported by \emph{ab-initio} density-functional theory calculations.</description><identifier>EISSN: 2331-8422</identifier><identifier>DOI: 10.48550/arxiv.1212.5087</identifier><language>eng</language><publisher>Ithaca: Cornell University Library, arXiv.org</publisher><subject>Critical temperature ; Density functional theory ; External pressure ; Ferromagnetism ; Hydrostatic pressure ; Magnetic properties ; Magnetism ; Muons ; Organic chemistry ; Physics - Strongly Correlated Electrons</subject><ispartof>arXiv.org, 2012-12</ispartof><rights>2012. This work is published under http://arxiv.org/licenses/nonexclusive-distrib/1.0/ (the “License”). 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Zero-field measurements show that the electrons localized on the Pr\(^{3+}\) ions do not play any role in the static magnetic properties of the compounds. Magnetism at the local level is indeed fully dominated by the weakly-itinerant ferromagnetism from the Co sublattice only. The increase of the chemical pressure triggered by the different ionic radii of La\(^{3+}\) and Pr\(^{3+}\), on the other hand, plays a crucial role in enhancing the value of the magnetic critical temperature and can be mimicked by the application of external hydrostatic pressure up to 24 kbar. A sharp discontinuity in the local magnetic field at the muon site in LaCoPO at around 5 kbar suggests a sizeable modification in the band structure of the material upon increasing pressure. This scenario is qualitatively supported by \emph{ab-initio} density-functional theory calculations.</description><subject>Critical temperature</subject><subject>Density functional theory</subject><subject>External pressure</subject><subject>Ferromagnetism</subject><subject>Hydrostatic pressure</subject><subject>Magnetic properties</subject><subject>Magnetism</subject><subject>Muons</subject><subject>Organic chemistry</subject><subject>Physics - Strongly Correlated Electrons</subject><issn>2331-8422</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GOX</sourceid><recordid>eNotkM1Lw0AQxRdBsNTePcmCFwVTd2c7yebgQUL8gEBL6T1sNrs2pUnqbir1v3djvcwwvB_De4-QG87mC4nInpQ7Nd9zDhzmyGRyQSYgBI_kAuCKzLzfMcYgTgBRTIjO-rbtO2qsNXqgvaV6a9pGqz1VXU3NaTCuC8fBGe-PYdAAD1tDW_XZmaHRQekPxg3NKFm6zrN-taT365w-00I90pV7uCaXVu29mf3vKdm85pvsPSqWbx_ZSxEp5BClAozgUinLla2A1ynYWNgkRY0itsGurkEkyFIErFNl5CKudYWayVpVmokpuT2__SugPLimVe6nHIsoxyICcHcGguWvo_FDueuPYzpfApMoQPAUxC9XhV8X</recordid><startdate>20121220</startdate><enddate>20121220</enddate><creator>Prando, G</creator><creator>Bonfà, P</creator><creator>Profeta, G</creator><creator>Khasanov, R</creator><creator>Bernardini, F</creator><creator>Mazzani, M</creator><creator>Brüning, E M</creator><creator>Pal, A</creator><creator>Awana, V P S</creator><creator>H -J Grafe</creator><creator>Büchner, B</creator><creator>De Renzi, R</creator><creator>Carretta, P</creator><creator>Sanna, S</creator><general>Cornell University Library, arXiv.org</general><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>GOX</scope></search><sort><creationdate>20121220</creationdate><title>Common effect of chemical and external pressures on the magnetic properties of RECoPO (RE = La, Pr)</title><author>Prando, G ; Bonfà, P ; Profeta, G ; Khasanov, R ; Bernardini, F ; Mazzani, M ; Brüning, E M ; Pal, A ; Awana, V P S ; H -J Grafe ; Büchner, B ; De Renzi, R ; Carretta, P ; Sanna, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a512-932e318aaf1afb21d92f63f795c536f255cd237509525d9ae846dcb5c08dabc03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Critical temperature</topic><topic>Density functional theory</topic><topic>External pressure</topic><topic>Ferromagnetism</topic><topic>Hydrostatic pressure</topic><topic>Magnetic properties</topic><topic>Magnetism</topic><topic>Muons</topic><topic>Organic chemistry</topic><topic>Physics - Strongly Correlated Electrons</topic><toplevel>online_resources</toplevel><creatorcontrib>Prando, G</creatorcontrib><creatorcontrib>Bonfà, P</creatorcontrib><creatorcontrib>Profeta, G</creatorcontrib><creatorcontrib>Khasanov, R</creatorcontrib><creatorcontrib>Bernardini, F</creatorcontrib><creatorcontrib>Mazzani, M</creatorcontrib><creatorcontrib>Brüning, E M</creatorcontrib><creatorcontrib>Pal, A</creatorcontrib><creatorcontrib>Awana, V P S</creatorcontrib><creatorcontrib>H -J Grafe</creatorcontrib><creatorcontrib>Büchner, B</creatorcontrib><creatorcontrib>De Renzi, R</creatorcontrib><creatorcontrib>Carretta, P</creatorcontrib><creatorcontrib>Sanna, S</creatorcontrib><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>arXiv.org</collection><jtitle>arXiv.org</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Prando, G</au><au>Bonfà, P</au><au>Profeta, G</au><au>Khasanov, R</au><au>Bernardini, F</au><au>Mazzani, M</au><au>Brüning, E M</au><au>Pal, A</au><au>Awana, V P S</au><au>H -J Grafe</au><au>Büchner, B</au><au>De Renzi, R</au><au>Carretta, P</au><au>Sanna, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Common effect of chemical and external pressures on the magnetic properties of RECoPO (RE = La, Pr)</atitle><jtitle>arXiv.org</jtitle><date>2012-12-20</date><risdate>2012</risdate><eissn>2331-8422</eissn><abstract>We report a detailed investigation of RECoPO (RE = La, Pr) and LaCoAsO materials performed by means of muon spin spectroscopy. Zero-field measurements show that the electrons localized on the Pr\(^{3+}\) ions do not play any role in the static magnetic properties of the compounds. Magnetism at the local level is indeed fully dominated by the weakly-itinerant ferromagnetism from the Co sublattice only. The increase of the chemical pressure triggered by the different ionic radii of La\(^{3+}\) and Pr\(^{3+}\), on the other hand, plays a crucial role in enhancing the value of the magnetic critical temperature and can be mimicked by the application of external hydrostatic pressure up to 24 kbar. A sharp discontinuity in the local magnetic field at the muon site in LaCoPO at around 5 kbar suggests a sizeable modification in the band structure of the material upon increasing pressure. 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subjects | Critical temperature Density functional theory External pressure Ferromagnetism Hydrostatic pressure Magnetic properties Magnetism Muons Organic chemistry Physics - Strongly Correlated Electrons |
title | Common effect of chemical and external pressures on the magnetic properties of RECoPO (RE = La, Pr) |
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