Common effect of chemical and external pressures on the magnetic properties of RECoPO (RE = La, Pr)

We report a detailed investigation of RECoPO (RE = La, Pr) and LaCoAsO materials performed by means of muon spin spectroscopy. Zero-field measurements show that the electrons localized on the Pr\(^{3+}\) ions do not play any role in the static magnetic properties of the compounds. Magnetism at the l...

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Hauptverfasser: Prando, G, Bonfà, P, Profeta, G, Khasanov, R, Bernardini, F, Mazzani, M, Brüning, E M, Pal, A, Awana, V P S, H -J Grafe, Büchner, B, De Renzi, R, Carretta, P, Sanna, S
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container_title arXiv.org
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creator Prando, G
Bonfà, P
Profeta, G
Khasanov, R
Bernardini, F
Mazzani, M
Brüning, E M
Pal, A
Awana, V P S
H -J Grafe
Büchner, B
De Renzi, R
Carretta, P
Sanna, S
description We report a detailed investigation of RECoPO (RE = La, Pr) and LaCoAsO materials performed by means of muon spin spectroscopy. Zero-field measurements show that the electrons localized on the Pr\(^{3+}\) ions do not play any role in the static magnetic properties of the compounds. Magnetism at the local level is indeed fully dominated by the weakly-itinerant ferromagnetism from the Co sublattice only. The increase of the chemical pressure triggered by the different ionic radii of La\(^{3+}\) and Pr\(^{3+}\), on the other hand, plays a crucial role in enhancing the value of the magnetic critical temperature and can be mimicked by the application of external hydrostatic pressure up to 24 kbar. A sharp discontinuity in the local magnetic field at the muon site in LaCoPO at around 5 kbar suggests a sizeable modification in the band structure of the material upon increasing pressure. This scenario is qualitatively supported by \emph{ab-initio} density-functional theory calculations.
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subjects Critical temperature
Density functional theory
External pressure
Ferromagnetism
Hydrostatic pressure
Magnetic properties
Magnetism
Muons
Organic chemistry
Physics - Strongly Correlated Electrons
title Common effect of chemical and external pressures on the magnetic properties of RECoPO (RE = La, Pr)
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