Crystal engineering using functionalized adamantane
We performed a first principles investigation on the structural, electronic, and optical properties of crystals made of chemically functionalized adamantane molecules. Several molecular building blocks, formed by boron and nitrogen substitutional functionalizations, were considered to build zincblen...
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| creator | Joelson Cott Garcia Assali, L V C Machado, W V M Justo, J F |
| description | We performed a first principles investigation on the structural, electronic, and optical properties of crystals made of chemically functionalized adamantane molecules. Several molecular building blocks, formed by boron and nitrogen substitutional functionalizations, were considered to build zincblende and wurtzite crystals, and the resulting structures presented large bulk moduli and cohesive energies, wide and direct bandgaps, and low dielectric constants (low-\(\kappa\) materials). Those properties provide stability for such structures up to room temperature, superior to those of typical molecular crystals. This indicates a possible road map for crystal engineering using functionalized diamondoids, with potential applications ranging from space filling between conducting wires in nanodevices to nano-electro-mechanical systems. |
| doi_str_mv | 10.48550/arxiv.1204.2863 |
| format | Article |
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Several molecular building blocks, formed by boron and nitrogen substitutional functionalizations, were considered to build zincblende and wurtzite crystals, and the resulting structures presented large bulk moduli and cohesive energies, wide and direct bandgaps, and low dielectric constants (low-\(\kappa\) materials). Those properties provide stability for such structures up to room temperature, superior to those of typical molecular crystals. 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| subjects | Boron Crystal structure Crystals Diamonds Dielectric properties First principles Mechanical systems Nanotechnology devices Optical properties Organic chemistry Physics - Materials Science Structural stability Wurtzite Zincblende |
| title | Crystal engineering using functionalized adamantane |
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