Probing isotope effects in chemical reactions using single ions

Isotope effects in reactions between Mg+ in the 3p 2P3/2 excited state and molecular hydrogen at thermal energies are studied through single reaction events. From only ~250 reactions with HD, the branching ratio between formation of MgD+ and MgH+ is found to be larger than 5. From additional 65 reac...

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Veröffentlicht in:arXiv.org 2008-02
Hauptverfasser: Staanum, Peter F, Hoejbjerre, Klaus, Wester, Roland, Drewsen, Michael
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Sprache:eng
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