Amphiphile Adsorption on Rigid Polyelectrolytes

Amphiphile Adsorption on Rigid Polyelectrolytes

A theory is presented which quantitatively accounts for the cooperative adsorption of cationic surfactants to anionic polyelectrolytes. For high salt concentration we find that the critical adsorption concentration (CAC) is a bilinear function of the polyion monomer and salt concentrations, with the...

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Veröffentlicht in:arXiv.org 2007-09
Hauptverfasser: Kuhn, Paulo S, Levin, Yan, Barbosa, Marcia C, Ana Paula Ravazzolo
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Sprache:eng
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Adsorption
Physics - Soft Condensed Matter
Physics - Statistical Mechanics
Polyelectrolytes
Salt
Surfactants
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Levin, Yan
Barbosa, Marcia C
Ana Paula Ravazzolo
description A theory is presented which quantitatively accounts for the cooperative adsorption of cationic surfactants to anionic polyelectrolytes. For high salt concentration we find that the critical adsorption concentration (CAC) is a bilinear function of the polyion monomer and salt concentrations, with the coefficients dependent only on the type of surfactant used. The results presented in the paper might be useful for designing more efficient gene delivery systems.
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subjects Adsorption
Physics - Soft Condensed Matter
Physics - Statistical Mechanics
Polyelectrolytes
Salt
Surfactants
title Amphiphile Adsorption on Rigid Polyelectrolytes
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