Kinetics and Mechanism of the Hydrogenation of the CpCr(CO)3 •/[CpCr(CO)3]2 Equilibrium to CpCr(CO)3H

The kinetics of the hydrogenation of 2 CpCr(CO)3 •/[CpCr(CO)3]2 to CpCr(CO)3H has been investigated. The reaction is second-order in Cr and first-order in H2, with a rate constant (if the rate law is written with [CpCr(CO)3 •]2) of 12(2) M–2 s–1 at 25 °C in benzene. DFT calculations rule out a side-...

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Veröffentlicht in:	Organometallics 2014-05, Vol.33 (10), p.2496-2502
Hauptverfasser:	Norton, Jack R, Spataru, Tudor, Camaioni, Donald M, Lee, Suh-Jane, Li, Gang, Choi, Jongwook, Franz, James A
Format:	Artikel
Sprache:	eng
Schlagworte:	1/12/15-tjl-Added UP# 34000 per D Baxter and A Gilbert Environmental Molecular Sciences Laboratory
Online-Zugang:	Volltext
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