Bis(diethylphosphino)methane As a Bridging Ligand in Complexes of Ir2, Rh2, and IrRh: Geminal C–H Activation of α-Olefins

Bis­(diethylphosphino)­methane (depm, Et2PCH2PEt2) is used as a new bridging ligand for the syntheses of a series of diiridium, dirhodium, and iridium/rhodium complexes, starting from trans-[MM′Cl2(CO)2(depm)2] (M = M′ = Ir (1); M = M′ = Rh (11); M = Ir, M′ = Rh (19)). The reduction of all three chl...

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Veröffentlicht in:	Organometallics 2012-03, Vol.31 (6), p.2286-2301
Hauptverfasser:	Slaney, Michael E, Anderson, D. Jason, Ferguson, Michael J, McDonald, Robert, Cowie, Martin
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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