Mechanism and Activation Parameters for the κO to μ,κ2 O,O′ Bonding Mode of the Maleic Acid Ligand on an Osmium Carbonyl Cluster

The reaction of maleic acid and [Os3(CO)10(NCCH3)2] afforded initially the cluster [Os3(μ-H)(CO)10(O2CCHCHCO2H)(CH3CN)], in which the maleic acid was κO bonded. This slowly converted to [Os3(μ-H)(CO)10(μ-O2CCHCHCO2H)], in which the ligand adopted the more usual μ,κ2 O,O′ bonding mode. The conversi...

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Veröffentlicht in:	Organometallics 2011-08, Vol.30 (15), p.3966-3970
Hauptverfasser:	Ganguly, Rakesh, Leong, Weng Kee
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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