Coordination Behavior and Transformations of Thienyl-Substituted Diacetylenes upon Coordination to Os3H2(CO)10

The reaction between 2- and 3-thienyl-substituted 1,3-butadiynes and the electron-deficient osmium cluster Os3H2(CO)10 yields trinuclear coordination products, associated with transformations of the diacetylene ligands. Depending on the heteroaryl end groups, osmium clusters with both a closed and o...

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Veröffentlicht in:Organometallics 2011-08, Vol.30 (15), p.3955-3965
Hauptverfasser: Brayshaw, Simon K, Clarke, Lionel P, Homanen, Pertti, Koentjoro, Olivia F, Warren, John E, Raithby, Paul R
Format: Artikel
Sprache:eng
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