Synthesis and Reactivity of [(PhB(CH2PPh2)3-κ3 P)Ru(NCMe)3]PF6 and Its Potential as a Transfer Hydrogenation Catalyst

The acetonitrile ligands in [(PhB(CH2PPh2)3-κ3 P)Ru(NCMe)3]PF6 (1) (which contains a facially coordinated anionic tripodal phosphine ligand) are labile and are rapidly replaced by other ligands, although the steric profile of the phosphine ligand limits the size and the number of the incoming ligand...

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Veröffentlicht in:	Organometallics 2010-11, Vol.29 (22), p.6121-6124
Hauptverfasser:	Walker, Jesse M, Cox, Alex M, Wang, Ruiyao, Spivak, Gregory J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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