Synthesis and Reactivity of NiII(Phpy)2 (Phpy = 2-Phenylpyridine)

This article describes the synthesis and reactivity of NiII(Phpy)2 (Phpy = 2-phenylpyridine) with a variety of oxidants, including O2, Br2, PhICl2, N-fluoropyridinium salts, CuII salts, and N-halosuccinimides. High-oxidation-state Ni intermediates were not detected in any of these transformations. I...

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Veröffentlicht in:	Organometallics 2010-11, Vol.29 (21), p.5446-5449
Hauptverfasser:	Higgs, Andrew T, Zinn, Paul J, Sanford, Melanie S
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Sprache:	eng ; jpn
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description	This article describes the synthesis and reactivity of NiII(Phpy)2 (Phpy = 2-phenylpyridine) with a variety of oxidants, including O2, Br2, PhICl2, N-fluoropyridinium salts, CuII salts, and N-halosuccinimides. High-oxidation-state Ni intermediates were not detected in any of these transformations. In all cases, the major organic product resulted from oxidatively induced C−C bond formation to generate the Phpy−Phpy dimer. Traces (2−16%) of organic products resulting from C−O, C−Br, C−Cl, and C−N bond-forming reductive elimination were also observed.
doi_str_mv	10.1021/om100387z
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title	Synthesis and Reactivity of NiII(Phpy)2 (Phpy = 2-Phenylpyridine)
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