Electric Field Reversal of Na2SO4, (NH4)2SO4, and Na2CO3 Relative to CaCl2 and NaCl at the Air/Aqueous Interface Revealed by Heterodyne Detected Phase-Sensitive Sum Frequency
Phase-sensitive sum frequency generation (PS-SFG) spectroscopy, heterodyne detected, was used to investigate the average direction of the transition dipole moment of interfacial water molecules that is intrinsically contained in the sign of the second-order nonlinear susceptibility, χ(2). The organi...
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Veröffentlicht in: | The journal of physical chemistry letters 2011-10, Vol.2 (20), p.2515-2520 |
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Sprache: | eng ; jpn |
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