Water Deprotonation via Oxo-Bridge Hydroxylation and 18O‑Exchange in Free Tetra-Manganese Oxide Clusters

One of the fundamental biological reactions, the catalytically activated water-splitting, takes place at an inorganic tetra-manganese monocalcium penta-oxygen (Mn4CaO5) cluster which together with its protein ligands forms the oxygen evolution complex (OEC) of the membrane-bound pigment–protein phot...

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Veröffentlicht in:	Journal of physical chemistry. C 2015-01
Hauptverfasser:	Lang, Sandra M, Fleischer, Irene, Bernhardt, Thorsten M, Barnett, Robert N, Landman, Uzi
Format:	Artikel
Sprache:	eng ; jpn
Online-Zugang:	Volltext
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