New Route for Stabilization of 1T-WS2 and MoS2 Phases

New Route for Stabilization of 1T-WS2 and MoS2 Phases

The phenomenon of a partial 2H→1T phase transition within multiwalled WS2 nanotubes under substitutional rhenium doping is discovered by means of high-resolution transmission electron microscopy. Using density-functional tight-binding calculations for the related MoS2 compound, we consider a possibl...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of physical chemistry. C 2011-12, Vol.115 (50), p.24586-24591
Hauptverfasser: Enyashin, Andrey N, Yadgarov, Lena, Houben, Lothar, Popov, Igor, Weidenbach, Marc, Tenne, Reshef, Bar-Sadan, Maya, Seifert, Gotthard
Format: Artikel
Sprache:eng
Schlagworte:
C: Nanops and Nanostructures
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 24591
container_issue 50
container_start_page 24586
container_title Journal of physical chemistry. C
container_volume 115
creator Enyashin, Andrey N
Yadgarov, Lena
Houben, Lothar
Popov, Igor
Weidenbach, Marc
Tenne, Reshef
Bar-Sadan, Maya
Seifert, Gotthard
description The phenomenon of a partial 2H→1T phase transition within multiwalled WS2 nanotubes under substitutional rhenium doping is discovered by means of high-resolution transmission electron microscopy. Using density-functional tight-binding calculations for the related MoS2 compound, we consider a possible origin of this phase transition, which was known formerly only for WS2 and MoS2 intercalated by alkali metals. An interplay between the stability of layered or nanotubular forms of 2H and 1T allotropes is found to be intimately related with their electronic structures and electro-donating ability of an impurity.
doi_str_mv 10.1021/jp2076325
format Article
fullrecord <record><control><sourceid>acs</sourceid><recordid>TN_cdi_acs_journals_10_1021_jp2076325</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d130599080</sourcerecordid><originalsourceid>FETCH-LOGICAL-a216t-9f25a35ad29392935cc2ebf5574f935bebc0ba2c959c166a0de433d54ac311a33</originalsourceid><addsrcrecordid>eNo9j81LAzEUxIMoWKsH_4NcPEbz8vJ2yVGKX1A_sBWPy0s2wV3KRpotgn-9K0oPw_zmMsMIcQ76ErSBq_7T6LpCQwdiBg6Nqi3R4Z5tfSxOSum1JtSAM0FP8Uu-5t0YZcpbuRrZd5vum8cuDzInCWv1vjKSh1Y-5glePrjEciqOEm9KPPv3uXi7vVkv7tXy-e5hcb1UbKAalUuGGIlb49BNohBM9ImotmlKPvqgPZvgyAWoKtZttIgtWQ4IwIhzcfHXy6E0fd5th2mtAd38fm32X_EHXL5D9w</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>New Route for Stabilization of 1T-WS2 and MoS2 Phases</title><source>ACS Publications</source><creator>Enyashin, Andrey N ; Yadgarov, Lena ; Houben, Lothar ; Popov, Igor ; Weidenbach, Marc ; Tenne, Reshef ; Bar-Sadan, Maya ; Seifert, Gotthard</creator><creatorcontrib>Enyashin, Andrey N ; Yadgarov, Lena ; Houben, Lothar ; Popov, Igor ; Weidenbach, Marc ; Tenne, Reshef ; Bar-Sadan, Maya ; Seifert, Gotthard</creatorcontrib><description>The phenomenon of a partial 2H→1T phase transition within multiwalled WS2 nanotubes under substitutional rhenium doping is discovered by means of high-resolution transmission electron microscopy. Using density-functional tight-binding calculations for the related MoS2 compound, we consider a possible origin of this phase transition, which was known formerly only for WS2 and MoS2 intercalated by alkali metals. An interplay between the stability of layered or nanotubular forms of 2H and 1T allotropes is found to be intimately related with their electronic structures and electro-donating ability of an impurity.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/jp2076325</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>C: Nanops and Nanostructures</subject><ispartof>Journal of physical chemistry. C, 2011-12, Vol.115 (50), p.24586-24591</ispartof><rights>Copyright © 2011 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp2076325$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp2076325$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Enyashin, Andrey N</creatorcontrib><creatorcontrib>Yadgarov, Lena</creatorcontrib><creatorcontrib>Houben, Lothar</creatorcontrib><creatorcontrib>Popov, Igor</creatorcontrib><creatorcontrib>Weidenbach, Marc</creatorcontrib><creatorcontrib>Tenne, Reshef</creatorcontrib><creatorcontrib>Bar-Sadan, Maya</creatorcontrib><creatorcontrib>Seifert, Gotthard</creatorcontrib><title>New Route for Stabilization of 1T-WS2 and MoS2 Phases</title><title>Journal of physical chemistry. C</title><addtitle>J. Phys. Chem. C</addtitle><description>The phenomenon of a partial 2H→1T phase transition within multiwalled WS2 nanotubes under substitutional rhenium doping is discovered by means of high-resolution transmission electron microscopy. Using density-functional tight-binding calculations for the related MoS2 compound, we consider a possible origin of this phase transition, which was known formerly only for WS2 and MoS2 intercalated by alkali metals. An interplay between the stability of layered or nanotubular forms of 2H and 1T allotropes is found to be intimately related with their electronic structures and electro-donating ability of an impurity.</description><subject>C: Nanops and Nanostructures</subject><issn>1932-7447</issn><issn>1932-7455</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNo9j81LAzEUxIMoWKsH_4NcPEbz8vJ2yVGKX1A_sBWPy0s2wV3KRpotgn-9K0oPw_zmMsMIcQ76ErSBq_7T6LpCQwdiBg6Nqi3R4Z5tfSxOSum1JtSAM0FP8Uu-5t0YZcpbuRrZd5vum8cuDzInCWv1vjKSh1Y-5glePrjEciqOEm9KPPv3uXi7vVkv7tXy-e5hcb1UbKAalUuGGIlb49BNohBM9ImotmlKPvqgPZvgyAWoKtZttIgtWQ4IwIhzcfHXy6E0fd5th2mtAd38fm32X_EHXL5D9w</recordid><startdate>20111222</startdate><enddate>20111222</enddate><creator>Enyashin, Andrey N</creator><creator>Yadgarov, Lena</creator><creator>Houben, Lothar</creator><creator>Popov, Igor</creator><creator>Weidenbach, Marc</creator><creator>Tenne, Reshef</creator><creator>Bar-Sadan, Maya</creator><creator>Seifert, Gotthard</creator><general>American Chemical Society</general><scope/></search><sort><creationdate>20111222</creationdate><title>New Route for Stabilization of 1T-WS2 and MoS2 Phases</title><author>Enyashin, Andrey N ; Yadgarov, Lena ; Houben, Lothar ; Popov, Igor ; Weidenbach, Marc ; Tenne, Reshef ; Bar-Sadan, Maya ; Seifert, Gotthard</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a216t-9f25a35ad29392935cc2ebf5574f935bebc0ba2c959c166a0de433d54ac311a33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>C: Nanops and Nanostructures</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Enyashin, Andrey N</creatorcontrib><creatorcontrib>Yadgarov, Lena</creatorcontrib><creatorcontrib>Houben, Lothar</creatorcontrib><creatorcontrib>Popov, Igor</creatorcontrib><creatorcontrib>Weidenbach, Marc</creatorcontrib><creatorcontrib>Tenne, Reshef</creatorcontrib><creatorcontrib>Bar-Sadan, Maya</creatorcontrib><creatorcontrib>Seifert, Gotthard</creatorcontrib><jtitle>Journal of physical chemistry. C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Enyashin, Andrey N</au><au>Yadgarov, Lena</au><au>Houben, Lothar</au><au>Popov, Igor</au><au>Weidenbach, Marc</au><au>Tenne, Reshef</au><au>Bar-Sadan, Maya</au><au>Seifert, Gotthard</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New Route for Stabilization of 1T-WS2 and MoS2 Phases</atitle><jtitle>Journal of physical chemistry. C</jtitle><addtitle>J. Phys. Chem. C</addtitle><date>2011-12-22</date><risdate>2011</risdate><volume>115</volume><issue>50</issue><spage>24586</spage><epage>24591</epage><pages>24586-24591</pages><issn>1932-7447</issn><eissn>1932-7455</eissn><abstract>The phenomenon of a partial 2H→1T phase transition within multiwalled WS2 nanotubes under substitutional rhenium doping is discovered by means of high-resolution transmission electron microscopy. Using density-functional tight-binding calculations for the related MoS2 compound, we consider a possible origin of this phase transition, which was known formerly only for WS2 and MoS2 intercalated by alkali metals. An interplay between the stability of layered or nanotubular forms of 2H and 1T allotropes is found to be intimately related with their electronic structures and electro-donating ability of an impurity.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp2076325</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1932-7447
ispartof Journal of physical chemistry. C, 2011-12, Vol.115 (50), p.24586-24591
issn 1932-7447
1932-7455
language eng
recordid cdi_acs_journals_10_1021_jp2076325
source ACS Publications
subjects C: Nanops and Nanostructures
title New Route for Stabilization of 1T-WS2 and MoS2 Phases
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-20T02%3A52%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=New%20Route%20for%20Stabilization%20of%201T-WS2%20and%20MoS2%20Phases&rft.jtitle=Journal%20of%20physical%20chemistry.%20C&rft.au=Enyashin,%20Andrey%20N&rft.date=2011-12-22&rft.volume=115&rft.issue=50&rft.spage=24586&rft.epage=24591&rft.pages=24586-24591&rft.issn=1932-7447&rft.eissn=1932-7455&rft_id=info:doi/10.1021/jp2076325&rft_dat=%3Cacs%3Ed130599080%3C/acs%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true