Percolation-Induced Ferrimagnetism from Vacancy Order in [Gua]Mn1–x Fe2x/3(HCOO)3 Hybrid Perovskites

Percolation-Induced Ferrimagnetism from Vacancy Order in [Gua]Mn1–x Fe2x/3(HCOO)3 Hybrid Perovskites

We report the magnetic behavior of the hybrid perovskites [Gua]­Mn1–x Fe2x/3□ x/3(HCOO)3 (0 ≤ x ≤ 0.88), showing that vacancy ordering drives bulk ferrimagnetism for x > 0.6. The behavior is rationalized in terms of a simple microscopic model of percolation-induced ferrimagnetism. Monte Carlo sim...

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Veröffentlicht in:Journal of the American Chemical Society 2024-05, Vol.146 (20), p.13714-13718
Hauptverfasser: Bulled, Johnathan M., Willis, Alexandra, Faure Beaulieu, Zoé, Cassidy, Simon J., Bruckmoser, Jonas, Boström, Hanna L. B., Goodwin, Andrew L.
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container_end_page 13718
container_issue 20
container_start_page 13714
container_title Journal of the American Chemical Society
container_volume 146
creator Bulled, Johnathan M.
Willis, Alexandra
Faure Beaulieu, Zoé
Cassidy, Simon J.
Bruckmoser, Jonas
Boström, Hanna L. B.
Goodwin, Andrew L.
description We report the magnetic behavior of the hybrid perovskites [Gua]­Mn1–x Fe2x/3□ x/3(HCOO)3 (0 ≤ x ≤ 0.88), showing that vacancy ordering drives bulk ferrimagnetism for x > 0.6. The behavior is rationalized in terms of a simple microscopic model of percolation-induced ferrimagnetism. Monte Carlo simulations driven by this model reproduce the experimental dependence of magnetic susceptibility on x and show that, at intermediate compositions, domains of short-range vacancy order lead to the emergence of local magnetization. Our results open up a new avenue for the design of multiferroic hybrid perovskites.
doi_str_mv 10.1021/jacs.4c03407
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title Percolation-Induced Ferrimagnetism from Vacancy Order in [Gua]Mn1–x Fe2x/3(HCOO)3 Hybrid Perovskites
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