Synthesis of Alkenylboronates from N‑Tosylhydrazones through Palladium-Catalyzed Carbene Migratory Insertion

The palladium-catalyzed oxidative borylation reaction of N-tosylhydrazones has been developed. The reaction features mild conditions, broad substrate scope, and good functional group tolerance. It thus represents a highly efficient and practical method for the synthesis of di-, tri-, and tetrasubsti...

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Veröffentlicht in:	Journal of the American Chemical Society 2021-07, Vol.143 (26), p.9769-9780
Hauptverfasser:	Ping, Yifan, Wang, Rui, Wang, Qianyue, Chang, Taiwei, Huo, Jingfeng, Lei, Ming, Wang, Jianbo
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Online-Zugang:	Volltext
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