A Neutral Ga6 Octahedron: Synthesis, Structure, and Aromaticity

A Neutral Ga6 Octahedron: Synthesis, Structure, and Aromaticity

Potassium graphite reduction of L:Ga(Mes)Cl2 [L: = :C{(i-Pr)NC(Me)}2, Mes = 2,4,6-Me3C6H2] (1) in hexane yields the organogallium dimer L:(Mes)(Cl)Ga−Ga(Cl)(Mes):L (2), while potassium reduction of 1 in toluene affords the neutral aromatic Ga6 octahedron L:Ga[Ga4Mes4]Ga:L (3).

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Veröffentlicht in:Journal of the American Chemical Society 2009-03, Vol.131 (9), p.3168-3169
Hauptverfasser: Quillian, Brandon, Wei, Pingrong, Wannere, Chaitanya S., Schleyer, Paul v. R., Robinson, Gregory H.
Format: Artikel
Sprache:eng ; jpn
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Zusammenfassung:Potassium graphite reduction of L:Ga(Mes)Cl2 [L: = :C{(i-Pr)NC(Me)}2, Mes = 2,4,6-Me3C6H2] (1) in hexane yields the organogallium dimer L:(Mes)(Cl)Ga−Ga(Cl)(Mes):L (2), while potassium reduction of 1 in toluene affords the neutral aromatic Ga6 octahedron L:Ga[Ga4Mes4]Ga:L (3).
ISSN:0002-7863
1520-5126
DOI:10.1021/ja809945v