Photoswitching of a Thermally Unswitchable Molecular Magnet Cu(hfac)2Li‑Pr Evidenced by Steady-State and Time-Resolved Electron Paramagnetic Resonance

Most photoswitchable molecular magnets exhibit thermally induced switching, as is typical of spin crossover (SCO), valence tautomerism and SCO-like phenomena. We report a rare case of a copper-nitroxide based molecular magnet Cu­(hfac)2L i‑Pr that does not exhibit quantitative SCO-like behavior in t...

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Veröffentlicht in:	Journal of the American Chemical Society 2014-07, Vol.136 (28), p.10132-10138
Hauptverfasser:	Barskaya, Irina Yu, Tretyakov, Evgeny V, Sagdeev, Renad Z, Ovcharenko, Victor I, Bagryanskaya, Elena G, Maryunina, Kseniya Yu, Takui, Takeji, Sato, Kazunobu, Fedin, Matvey V
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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