Polyoxometalate-Catalyzed Insertion of Oxygen from O2 into Tin–Alkyl Bonds

The polyoxometalate H5PV2Mo10O40 mediates the insertion of an oxygen atom from H5PV2Mo10O40 into the tin–carbon bond of n-Bu4Sn through its activation by electron transfer to yield 1-butanol and (n-Bu3Sn)2O. The reaction is initiated by electron transfer from n-Bu4Sn to H5PVV 2Mo10O40 to yield the i...

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Veröffentlicht in:	Journal of the American Chemical Society 2013-12, Vol.135 (51), p.19304-19310
Hauptverfasser:	Khenkin, Alexander M, Efremenko, Irena, Martin, Jan M. L, Neumann, Ronny
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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