Raising the pK a Limit of “Soft” Nucleophiles in Palladium-Catalyzed Allylic Substitutions: Application of Diarylmethane Pronucleophiles

The Tsuji–Trost allylic substitution reaction provides a useful and efficient approach to construct C–C bonds between sp3-hybridized carbons. The widely accepted paradigm for classifying the mode of attack of nucleophiles on palladium π-allyl intermediates in the Tsuji–Trost reaction is based on the...

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Veröffentlicht in:	Journal of the American Chemical Society 2013-11, Vol.135 (46), p.17602-17609
Hauptverfasser:	Sha, Sheng-Chun, Zhang, Jiadi, Carroll, Patrick J, Walsh, Patrick J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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