Investigating the α‑Effect in Gas-Phase SN2 Reactions of Microsolvated Anions

The α-effectenhanced reactivity of nucleophiles with a lone-pair adjacent to the attacking centerwas recently demonstrated for gas-phase SN2 reactions of HOO–, supporting an intrinsic component of the α-effect. In the present work we explore the gas-phase reactivity of microsolvated nucleophiles i...

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Veröffentlicht in:	Journal of the American Chemical Society 2013-10, Vol.135 (41), p.15508-15514
Hauptverfasser:	Thomsen, Ditte L, Reece, Jennifer N, Nichols, Charles M, Hammerum, Steen, Bierbaum, Veronica M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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