The Sixteen CB11H n Me12 - n - Anions with Fivefold Substitution Symmetry:  Anodic Oxidation and Electronic Structure

The 15 symmetrically methylated derivatives of the CB11H12 - anion (1a) have been synthesized and found to vary greatly in ease of oxidation. Cyclic voltammetry in liquid SO2 yielded fully reversible oxidation potentials for five of those that have no adjacent unsubstituted vertices in positions 7−1...

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Veröffentlicht in:	Journal of the American Chemical Society 2007-10, Vol.129 (43), p.12960-12980
Hauptverfasser:	King, Benjamin T, Körbe, Stefanie, Schreiber, Peter J, Clayton, Joshua, Němcová, Adriana, Havlas, Zdeněk, Vyakaranam, Kamesh, Fete, Matthew G, Zharov, Ilya, Ceremuga, Jason, Michl, Josef
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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