Polysulfide Anions II:  Structure and Vibrational Spectra of the S4 2- and S5 2- Anions. Influence of the Cations on Bond Length, Valence, and Torsion Angle

The influence of the cations on bond length, valence, and torsion angle of S4 2- and S5 2- anions was examined in a series of solid alkali tetra- and pentasulfides by relating their Raman spectra to their known X-ray structures through a force-field analysis. The IR and Raman spectra of BaS4·H2O and...

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Veröffentlicht in:	Inorganic chemistry 2000-06, Vol.39 (12), p.2593-2603
Hauptverfasser:	El Jaroudi, Omar, Picquenard, Eric, Demortier, Antoine, Lelieur, Jean-Pierre, Corset, Jacques
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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