One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation

One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation

The reaction of [W(CN)6(bpy)]− with the corresponding Mn Schiff bases led to the formation of two antiferromagnetic (1) and ferromagnetic (2) chains. The formation of the conglomerate (2) is associated with chiral induction by the enantiomeric chelate-ring conformation of the Mn Schiff base. Modulat...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2009-10, Vol.48 (19), p.9066-9068
Hauptverfasser: Choi, Seok Woo, Ryu, Dae Won, Lee, Jin Wuk, Yoon, Jung Hee, Kim, Hyoung Chan, Lee, Hyosug, Cho, Beong Ki, Hong, Chang Seop
Format: Artikel
Sprache:eng ; jpn
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 9068
container_issue 19
container_start_page 9066
container_title Inorganic chemistry
container_volume 48
creator Choi, Seok Woo
Ryu, Dae Won
Lee, Jin Wuk
Yoon, Jung Hee
Kim, Hyoung Chan
Lee, Hyosug
Cho, Beong Ki
Hong, Chang Seop
description The reaction of [W(CN)6(bpy)]− with the corresponding Mn Schiff bases led to the formation of two antiferromagnetic (1) and ferromagnetic (2) chains. The formation of the conglomerate (2) is associated with chiral induction by the enantiomeric chelate-ring conformation of the Mn Schiff base. Modulation of the linking groups in the Mn Schiff bases affects the interchain contacts, causing alteration of the magnetic behaviors from metamagnetism (1) to slow magnetic relaxation (2).
doi_str_mv 10.1021/ic901610j
format Article
fullrecord <record><control><sourceid>acs</sourceid><recordid>TN_cdi_acs_journals_10_1021_ic901610j</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c529067021</sourcerecordid><originalsourceid>FETCH-LOGICAL-a968-32fc04789828485f24efdf0fa7ee77a754881c90bc0238c0cb21ac6b8377a5b83</originalsourceid><addsrcrecordid>eNo9kEtLAzEUhYMoWKsL_0E27jp6k3ll3NnxNdBSsEXdDbeZTEnJJKWZYl36z02puDqX-x0OnEPINYNbBpzdaVkAyxisT8iApRyilMHnKRkAhJtlWXFOLrxfA0ARJ9mA_Mysih51p6zXzqKh5Tda3ahovNXNSjV0aquq-nin4-Dp0Rgtaem6jVF75e_pNPw6XFnVa9-N6HzjbI9WuZ2nb8o7s-tD6oiibejcuC86PXploAb3eKCX5KxF49XVnw7J4vlpUb5Gk9lLVT5MIiwyEcW8lZDkohBcJCJteaLapoUWc6XyHPM0EYKF7ksJPBYS5JIzlNlSxIGmQYbk5hiL0tdrt9uGsr5mUB9mq_9ni38B-WNhRQ</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation</title><source>ACS Publications</source><creator>Choi, Seok Woo ; Ryu, Dae Won ; Lee, Jin Wuk ; Yoon, Jung Hee ; Kim, Hyoung Chan ; Lee, Hyosug ; Cho, Beong Ki ; Hong, Chang Seop</creator><creatorcontrib>Choi, Seok Woo ; Ryu, Dae Won ; Lee, Jin Wuk ; Yoon, Jung Hee ; Kim, Hyoung Chan ; Lee, Hyosug ; Cho, Beong Ki ; Hong, Chang Seop</creatorcontrib><description>The reaction of [W(CN)6(bpy)]− with the corresponding Mn Schiff bases led to the formation of two antiferromagnetic (1) and ferromagnetic (2) chains. The formation of the conglomerate (2) is associated with chiral induction by the enantiomeric chelate-ring conformation of the Mn Schiff base. Modulation of the linking groups in the Mn Schiff bases affects the interchain contacts, causing alteration of the magnetic behaviors from metamagnetism (1) to slow magnetic relaxation (2).</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic901610j</identifier><language>eng ; jpn</language><publisher>American Chemical Society</publisher><ispartof>Inorganic chemistry, 2009-10, Vol.48 (19), p.9066-9068</ispartof><rights>Copyright © 2009 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ic901610j$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ic901610j$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Choi, Seok Woo</creatorcontrib><creatorcontrib>Ryu, Dae Won</creatorcontrib><creatorcontrib>Lee, Jin Wuk</creatorcontrib><creatorcontrib>Yoon, Jung Hee</creatorcontrib><creatorcontrib>Kim, Hyoung Chan</creatorcontrib><creatorcontrib>Lee, Hyosug</creatorcontrib><creatorcontrib>Cho, Beong Ki</creatorcontrib><creatorcontrib>Hong, Chang Seop</creatorcontrib><title>One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation</title><title>Inorganic chemistry</title><addtitle>Inorg. Chem</addtitle><description>The reaction of [W(CN)6(bpy)]− with the corresponding Mn Schiff bases led to the formation of two antiferromagnetic (1) and ferromagnetic (2) chains. The formation of the conglomerate (2) is associated with chiral induction by the enantiomeric chelate-ring conformation of the Mn Schiff base. Modulation of the linking groups in the Mn Schiff bases affects the interchain contacts, causing alteration of the magnetic behaviors from metamagnetism (1) to slow magnetic relaxation (2).</description><issn>0020-1669</issn><issn>1520-510X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNo9kEtLAzEUhYMoWKsL_0E27jp6k3ll3NnxNdBSsEXdDbeZTEnJJKWZYl36z02puDqX-x0OnEPINYNbBpzdaVkAyxisT8iApRyilMHnKRkAhJtlWXFOLrxfA0ARJ9mA_Mysih51p6zXzqKh5Tda3ahovNXNSjV0aquq-nin4-Dp0Rgtaem6jVF75e_pNPw6XFnVa9-N6HzjbI9WuZ2nb8o7s-tD6oiibejcuC86PXploAb3eKCX5KxF49XVnw7J4vlpUb5Gk9lLVT5MIiwyEcW8lZDkohBcJCJteaLapoUWc6XyHPM0EYKF7ksJPBYS5JIzlNlSxIGmQYbk5hiL0tdrt9uGsr5mUB9mq_9ni38B-WNhRQ</recordid><startdate>20091005</startdate><enddate>20091005</enddate><creator>Choi, Seok Woo</creator><creator>Ryu, Dae Won</creator><creator>Lee, Jin Wuk</creator><creator>Yoon, Jung Hee</creator><creator>Kim, Hyoung Chan</creator><creator>Lee, Hyosug</creator><creator>Cho, Beong Ki</creator><creator>Hong, Chang Seop</creator><general>American Chemical Society</general><scope/></search><sort><creationdate>20091005</creationdate><title>One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation</title><author>Choi, Seok Woo ; Ryu, Dae Won ; Lee, Jin Wuk ; Yoon, Jung Hee ; Kim, Hyoung Chan ; Lee, Hyosug ; Cho, Beong Ki ; Hong, Chang Seop</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a968-32fc04789828485f24efdf0fa7ee77a754881c90bc0238c0cb21ac6b8377a5b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>2009</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Choi, Seok Woo</creatorcontrib><creatorcontrib>Ryu, Dae Won</creatorcontrib><creatorcontrib>Lee, Jin Wuk</creatorcontrib><creatorcontrib>Yoon, Jung Hee</creatorcontrib><creatorcontrib>Kim, Hyoung Chan</creatorcontrib><creatorcontrib>Lee, Hyosug</creatorcontrib><creatorcontrib>Cho, Beong Ki</creatorcontrib><creatorcontrib>Hong, Chang Seop</creatorcontrib><jtitle>Inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Choi, Seok Woo</au><au>Ryu, Dae Won</au><au>Lee, Jin Wuk</au><au>Yoon, Jung Hee</au><au>Kim, Hyoung Chan</au><au>Lee, Hyosug</au><au>Cho, Beong Ki</au><au>Hong, Chang Seop</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation</atitle><jtitle>Inorganic chemistry</jtitle><addtitle>Inorg. Chem</addtitle><date>2009-10-05</date><risdate>2009</risdate><volume>48</volume><issue>19</issue><spage>9066</spage><epage>9068</epage><pages>9066-9068</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>The reaction of [W(CN)6(bpy)]− with the corresponding Mn Schiff bases led to the formation of two antiferromagnetic (1) and ferromagnetic (2) chains. The formation of the conglomerate (2) is associated with chiral induction by the enantiomeric chelate-ring conformation of the Mn Schiff base. Modulation of the linking groups in the Mn Schiff bases affects the interchain contacts, causing alteration of the magnetic behaviors from metamagnetism (1) to slow magnetic relaxation (2).</abstract><pub>American Chemical Society</pub><doi>10.1021/ic901610j</doi><tpages>3</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0020-1669
ispartof Inorganic chemistry, 2009-10, Vol.48 (19), p.9066-9068
issn 0020-1669
1520-510X
language eng ; jpn
recordid cdi_acs_journals_10_1021_ic901610j
source ACS Publications
title One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-16T01%3A24%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=One-Dimensional%20Cyanide-Bridged%20MnIIIWV%20Bimetallic%20Complexes:%20Metamagnetism,%20Spontaneous%20Resolution,%20and%20Slow%20Magnetic%20Relaxation&rft.jtitle=Inorganic%20chemistry&rft.au=Choi,%20Seok%20Woo&rft.date=2009-10-05&rft.volume=48&rft.issue=19&rft.spage=9066&rft.epage=9068&rft.pages=9066-9068&rft.issn=0020-1669&rft.eissn=1520-510X&rft_id=info:doi/10.1021/ic901610j&rft_dat=%3Cacs%3Ec529067021%3C/acs%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true