Synthesis of [N(CH3)4]2O3SOSO2(s) and [N(CH3)4]2[(O2SO)2SO2]·SO2(s) Containing (SO4)(SO2) x 2– x = 1, 2, Members of a New Class of Sulfur Oxydianions

One mole equivalent of SO2 reversibly reacts with [N(CH3)4]2SO4(s) to give [N(CH3)4]2S2O6(s) (1) containing the [O3SOSO2]2–, shown by Raman and IR to be an isomer of the [O3SSO3]2– dianion. The experimental and calculated (B3PW91/6-311+G(3df)) vibrational spectra are in excellent agreement, and the...

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Veröffentlicht in:	Inorganic chemistry 2013-06, Vol.52 (12), p.7193-7202
Hauptverfasser:	Bruna, Pablo, Decken, Andreas, Grein, Friedrich, Passmore, Jack, Rautiainen, J. Mikko, Richardson, Stephanie, Whidden, Tom
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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