Ag(nic)2 (nic = Nicotinate): A Spin-Canted Quasi-2D Antiferromagnet Composed of Square-Planar S = 1/2 AgII Ions

Square-planar S = 1/2 AgII ions in polymeric Ag(nic)2 are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below T N = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction.

Bibliographische Detailangaben

Veröffentlicht in:	Inorganic chemistry 2012-02, Vol.51 (4), p.1989-1991
Hauptverfasser:	Manson, Jamie L, Woods, Toby J, Lapidus, Saul H, Stephens, Peter W, Southerland, Heather I, Zapf, Vivien S, Singleton, John, Goddard, Paul A, Lancaster, Tom, Steele, Andrew J, Blundell, Stephen J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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