Synthesis and Reactivity of Bis(tetramethylcyclopentadienyl) Yttrium Metallocenes Including the Reduction of Me3SiN3 to [(Me3Si)2N]− with [(C5Me4H)2Y(THF)]2(μ-η2:η2-N2)

The metallocene precursors needed to provide the tetramethylcyclopentadienyl yttrium complexes (C5Me4H)3Y, [(C5Me4H)2Y(THF)]2(μ-η2:η2-N2), and [(C5Me4H)2Y(μ-H)]2 for reactivity studies have been synthesized and fully characterized, and their reaction chemistry has led to an unexpected conversion of...

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Veröffentlicht in:	Inorganic chemistry 2010-07, Vol.49 (14), p.6655-6663
Hauptverfasser:	Lorenz, Sara E, Schmiege, Benjamin M, Lee, David S, Ziller, Joseph W, Evans, William J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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