Methyl Tin(IV) Derivatives of HOTeF5 and HN(SO2CF3)2: A Solution Multinuclear NMR Study and the X-ray Crystal Structures of (CH3)2SnCl(OTeF5) and [(CH3)3Sn(H2O)2][N(SO2CF3)2]
The new tin(IV) species (CH3)2SnCl(OTeF5) was prepared via either the solvolysis of (CH3)3SnCl in HOTeF5 or the reaction of (CH3)3SnCl with ClOTeF5. It was characterized by NMR and vibrational spectroscopy, mass spectrometry, and single crystal X-ray diffraction. (CH3)2SnCl(OTeF5) crystallizes in th...
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Veröffentlicht in: | Inorganic chemistry 2004-05, Vol.43 (10), p.3189-3199 |
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Hauptverfasser: | , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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