Photoelectrochemistry on RuII-2,2‘-bipyridine-phosphonate-Derivatized TiO2 with the I3 -/I- and Quinone/Hydroquinone Relays. Design of Photoelectrochemical Synthesis Cells

Photocurrent measurements have been made on nanocrystalline TiO2 surfaces derivatized by adsorption of a catalyst precursor, [Ru(tpy)(bpy(PO3H2)2)(OH2)]2+, or chromophore, [Ru(bpy)2(bpy(PO3H2)2)]2+ (tpy is 2,2‘:6‘,2‘ ‘-terpyridine, bpy is 2,2‘-bipyridine, and bpy(PO3H2)2 is 2,2‘-bipyridyl-4,4‘-dipho...

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Veröffentlicht in:Inorganic chemistry 2005-03, Vol.44 (6), p.2089-2097
Hauptverfasser: Gallagher, Laurie A, Serron, Scafford A, Wen, Xingu, Hornstein, Brooks J, Dattelbaum, D. M, Schoonover, J. R, Meyer, Thomas J
Format: Artikel
Sprache:eng
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