Thiolate-Mediated Selectivity Control in Aerobic Alcohol Oxidation by Porous Carbon-Supported Au25 Clusters

Supported Au25 clusters were prepared through the calcination of Au25(SC12H25)18 on hierarchically porous carbon nanosheets under vacuum at temperatures in the range of 400–500 °C for 2–4 h. TEM and EXAFS analyses revealed that the thiolate coverage on Au25 gradually decreased with increasing calcin...

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Veröffentlicht in:	ACS catalysis 2014-10, Vol.4 (10), p.3696-3700
Hauptverfasser:	Yoskamtorn, Tatchamapan, Yamazoe, Seiji, Takahata, Ryo, Nishigaki, Jun-ichi, Thivasasith, Anawat, Limtrakul, Jumras, Tsukuda, Tatsuya
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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