Advanced Vanadium Redox Flow Battery Facilitated by Synergistic Effects of the Co2P‑Modified Electrode

Redox flow batteries (RFBs) are considered a promising option for large-scale energy storage due to their ability to decouple energy and power, high safety, long durability, and easy scalability. However, the most advanced type of RFB, all-vanadium redox flow batteries (VRFBs), still encounters obst...

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Veröffentlicht in:ACS sustainable chemistry & engineering 2024-08, Vol.12 (34), p.12837-12844
Hauptverfasser: Huang, Yingjia, Xu, Jian, Huang, Xiaolei, He, Xinyan, Cao, Jinchao, Jia, Chuankun, Ding, Mei
Format: Artikel
Sprache:eng
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Zusammenfassung:Redox flow batteries (RFBs) are considered a promising option for large-scale energy storage due to their ability to decouple energy and power, high safety, long durability, and easy scalability. However, the most advanced type of RFB, all-vanadium redox flow batteries (VRFBs), still encounters obstacles such as low performance and high cost that hinder its commercial adoption. One of the factors contributing to the suboptimal performance of VRFBs is the insufficient electrochemical activity of electrodes, which impacts critical metrics including voltage efficiency (VE), energy efficiency (EE), power output, and cycling life. By utilizing cobalt phosphide (Co2P) to modify the carbon felt (CF), the resulting Co2P-CF composite demonstrates improved electrochemical activity toward the redox reactions of VO2 +/VO2+ couple. Theoretical calculations suggest that the adsorption energies of VO2+ and VO2 + ions onto Co2P-CF are lower than those onto bare CF, facilitating mass transfer in redox reactions. In conjunction with increased specific surface area, enhanced wettability, and improved conductivity, Co2P-CF as the cathode enhances the performance of the VRFB compared to that with the use of bare CF electrodes. Specifically, the power density reaches 1011.4 mW cm–2, representing a 33.5% enhancement over the VRFB cell based on bare CF. During an extended cycling process at 100 mA cm–2, the Co2P-CF-based cell demonstrates average VE and EE values of 88.2% and 86.4%, respectively, surpassing the bare CF-based cell, which exhibits VE and EE values of 76.4% and 74.9%. In this work, the enhancement of the advanced VRFB is achieved by incorporating Co2P onto the CF cathode. This approach offers a valuable blueprint for achieving high-performance VRFBs through a straightforward and easily implementable method.
ISSN:2168-0485
2168-0485
DOI:10.1021/acssuschemeng.4c03551